Si−C Bond Activation of ArMe2SiOH Promoted by a Bromoplatinum(II) Complex and Ag2O. Aryl Group Transfer from Silicon to Platinum

2001 ◽  
Vol 20 (6) ◽  
pp. 1243-1246 ◽  
Author(s):  
Neli Mintcheva ◽  
Yasushi Nishihara ◽  
Makoto Tanabe ◽  
Kazunori Hirabayashi ◽  
Atsunori Mori ◽  
...  
2018 ◽  
Vol 130 (30) ◽  
pp. 9449-9453 ◽  
Author(s):  
Raphael E. F. de Paiva ◽  
Zhifeng Du ◽  
Douglas H. Nakahata ◽  
Frederico A. Lima ◽  
Pedro P. Corbi ◽  
...  

Polyhedron ◽  
2021 ◽  
pp. 115550
Author(s):  
Purna C.R. Vasireddy ◽  
Akash R. Gogate ◽  
Dale R. Enright ◽  
Irina P. Smoliakova

2012 ◽  
Vol 124 (49) ◽  
pp. 12500-12504 ◽  
Author(s):  
Jingjing Wang ◽  
Weiqiang Chen ◽  
Sujing Zuo ◽  
Lu Liu ◽  
Xinrui Zhang ◽  
...  

2018 ◽  
Vol 47 (5) ◽  
pp. 1703-1708 ◽  
Author(s):  
Renzo N. Arias-Ugarte ◽  
Keith H. Pannell

Me4Pb and Ph4Pb readily transfer methyl or phenyl groups to an equivalent molar ratio of tin(iv) chlorides in the order SnCl4 > MeSnCl3 > Me2SnCl2 > Me3SnCl, often in a selective manner.


2008 ◽  
Vol 80 (5) ◽  
pp. 1155-1160 ◽  
Author(s):  
Hiromi Tobita ◽  
Nobukazu Yamahira ◽  
Keisuke Ohta ◽  
Takashi Komuro ◽  
Masaaki Okazaki

A new type of catalytic hydrosilylation of arylalkynes was induced by a 16-electron ruthenium bis(silyl) phosphine complex, resulting in ortho-silylation of the aryl group as well as a hydrogenation of the alkyne CC bond to give an (E)-form of alkene selectively. On the other hand, the same reaction using a related bis(silyl) complex having an η6-toluene ligand instead of the phosphine ligand as a catalyst led to a normal hydrosilylation reaction to afford silylalkene.


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