Addition of small molecules to (.eta.-C5H5)Rh2(.mu.-CO)(.mu.-CF3C2CF3). 7. Formation and properties of several isocyanide complexes (.eta.-C5H5)2Rh2(CO)(CNR)(.mu.-CF3C2CF3), crystal and molecular structure of the complex with R = 2,6-Me2C6H3, and structure and substituent influences on the electrochemistry of (.eta.-C5H5)2Rh2(CO)L(.mu.-CF3C2CF3) (L = CO, PPh3 or CNCMe3)

John W. Bixler; Alan M. Bond; Ron S. Dickson; Gary D. Fallon; Rhonda J. Nesbit; Helen. Pateras

doi:10.1021/om00155a009

Addition of small molecules to (.eta.-C5H5)Rh2(.mu.-CO)(.mu.-CF3C2CF3). 7. Formation and properties of several isocyanide complexes (.eta.-C5H5)2Rh2(CO)(CNR)(.mu.-CF3C2CF3), crystal and molecular structure of the complex with R = 2,6-Me2C6H3, and structure and substituent influences on the electrochemistry of (.eta.-C5H5)2Rh2(CO)L(.mu.-CF3C2CF3) (L = CO, PPh3 or CNCMe3)

Organometallics ◽

10.1021/om00155a009 ◽

1987 ◽

Vol 6 (12) ◽

pp. 2508-2517 ◽

Cited By ~ 8

Author(s):

John W. Bixler ◽

Alan M. Bond ◽

Ron S. Dickson ◽

Gary D. Fallon ◽

Rhonda J. Nesbit ◽

...

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure

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ChemInform Abstract: Insertions of Small Molecules CO, CH3NC, SO2, and CS2into the Pd - Pd σ-Bond of Pd2Cl2(PMe2CH2PMe2)2. Crystal and Molecular Structure of Pd2(μ-CO)Cl2(PMe2CH2PMe2)2.

Chemischer Informationsdienst ◽

10.1002/chin.198620293 ◽

1986 ◽

Vol 17 (20) ◽

Author(s):

M. L. KULLBERG ◽

C. P. KUBIAK

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure

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Synthesis of sulfidoosmium carbonyl cluster compounds by the photochemical decomposition of .mu.-(phenylthio)decacarbonylhydridotriosmium [HOs3(CO)10(.mu.-SPh)] and its subsequent reactions with selected small molecules. Synthesis and crystal and molecular structure of (.mu.3-sulfido)(.mu.3-carbonyl)nonacarbonyltriosmium [Os3(CO)9(.mu.3-CO)(.mu.3-S)]

Organometallics ◽

10.1021/om00082a006 ◽

1984 ◽

Vol 3 (4) ◽

pp. 548-552 ◽

Cited By ~ 29

Author(s):

Richard D. Adams ◽

Istvan T. Horvath ◽

Hoon Sik Kim

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure ◽

Cluster Compounds ◽

Carbonyl Cluster ◽

Photochemical Decomposition

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Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 8. Solution behavior of the isocyanide complexes (.eta.-C5H5)2Rh2(CO)(CNR)(CF3C2CF3) and their conversion to (.eta.-C5H5)2Rh2(CO){C(NR)C(CF3)C(CF3)}. Crystal and molecular structure of (.eta.-C5H5)2Rh2(CO){C(NEt)C(CF3)C(CF3)}

Organometallics ◽

10.1021/om00155a010 ◽

1987 ◽

Vol 6 (12) ◽

pp. 2517-2524 ◽

Cited By ~ 6

Author(s):

Ron S. Dickson ◽

Gary D. Fallon ◽

Rhonda J. Nesbit ◽

Helen. Pateras

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure ◽

Solution Behavior

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Synthesis and some reactions of binuclear η-cyclopentadienyl rhodium complexes containing bis(diphenylphosphino)methane and small molecules (CO, SO2, or SnCl2) as bridging ligands. Crystal and molecular structure of [Rh2(η-C5H5)2(µ-CO)(µ-Ph2PCH2PPh2)]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9840000533 ◽

1984 ◽

pp. 533-538 ◽

Cited By ~ 5

Author(s):

Felice Faraone ◽

Giuseppe Bruno ◽

Sandra Lo Schiavo ◽

Gabriella Bombieri

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure ◽

Rhodium Complexes ◽

Bridging Ligands

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Polylithiation of Small Molecules. Synthesis and Structure of the Functional Lithium Phosphide [Li(TMEDA)]2[PhPCMe2 C5H4]

Zeitschrift für Naturforschung B ◽

10.1515/znb-2000-1002 ◽

2000 ◽

Vol 55 (10) ◽

pp. 895-900 ◽

Cited By ~ 5

Author(s):

Ulrich Jürgen Bildmann ◽

Gerhard Müller

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure ◽

Orthorhombic Space Group ◽

Space Group

AbstractLithium Phosphides, Cyclopentadienides Treatment of 6,6-dimethylfulvene with LiPHPh in hexane/TMEDA (TMEDA = N,N,N′,N′- tetramethylethylenediamine) affords the monolithiated phosphinomethyl cyclopentadienide [Li(TMEDA)][PhHPCMe2C5H4] (1). Further reaction with LinBu in diethylether/TMEDA leads to the formation of the doubly lithiated phosphidomethyl cyclopentadienide [Li(TMEDA)]2[PhPCMe2C5H4] (2) whose crystal and molecular structure was determined (orthorhombic, space group P212121, a = 9.579(4), b = 12.788(2), c = 24.108(6) Å, Z = 4)

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Addition of small molecules to (.eta.-C5H5)2Rh2(CO)(CF3C2CF3). 2. Intramolecular reactions between .mu.-alkylidene groups and the .mu.-alkyne in some complexes (.eta.-C5H5)2Rh2(.mu.-CO)(.mu.-CR1R2)(.mu.-CF3C2CF3). Crystal and molecular structure of (.eta.-C5H5)2Rh2[.mu.-C(CF3):C(CF3)OC(OEt):C(CO2Et)]

Organometallics ◽

10.1021/om00121a029 ◽

1985 ◽

Vol 4 (2) ◽

pp. 355-359 ◽

Cited By ~ 21

Author(s):

Ron S. Dickson ◽

Gary D. Fallon ◽

Rhonda J. Nesbit ◽

Geoff N. Pain

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Crystal And Molecular Structure ◽

Intramolecular Reactions

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The addition of small molecules to (η-C5H5)2Rh2(CO)(CF3C2CF3)—IX. CH bond activation in the reactions with dienes, polyenes and arenes; the crystal and molecular structure of [(η-C5H5)2Rh2{C(CF3)C(CF3)H}]2(C6H4)

Polyhedron ◽

10.1016/s0277-5387(00)86308-1 ◽

1988 ◽

Vol 7 (10-11) ◽

pp. 859-870 ◽

Cited By ~ 12

Author(s):

Ron S. Dickson ◽

Susan M. Jenkins ◽

Brian W. Skelton ◽

Allan H. White

Keyword(s):

Molecular Structure ◽

Small Molecules ◽

Bond Activation ◽

Crystal And Molecular Structure

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Insertions of small molecules carbon monoxide, methyl isocyanide, sulfur dioxide, and carbon disulfide into the Pd-Pd .sigma.-bond of Pd2Cl2(PMe2CH2PMe2)2. Crystal and molecular structure of Pd2(.mu.-CO)Cl2(PMe2CH2PMe2)2

Inorganic Chemistry ◽

10.1021/ic00221a009 ◽

1986 ◽

Vol 25 (1) ◽

pp. 26-30 ◽

Cited By ~ 32

Author(s):

Marc L. Kullberg ◽

Clifford P. Kubiak

Keyword(s):

Molecular Structure ◽

Carbon Monoxide ◽

Sulfur Dioxide ◽

Small Molecules ◽

Carbon Disulfide ◽

Crystal And Molecular Structure ◽

Methyl Isocyanide ◽

Sigma Bond

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A neutron-diffraction study of the crystal and molecular structure of triphenylene*

Zeitschrift für Kristallographie ◽

10.1524/zkri.1973.138.138.113 ◽

1973 ◽

Vol 138 (138) ◽

pp. 113-128 ◽

Cited By ~ 26

Author(s):

G. Ferraris ◽

D. W. Jones ◽

J. Yerkess

Keyword(s):

Molecular Structure ◽

Neutron Diffraction ◽

Diffraction Study ◽

Crystal And Molecular Structure ◽

Neutron Diffraction Study

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The crystal and molecular structure of 9,10-dimethylphenanthrene

Zeitschrift für Kristallographie - Crystalline Materials ◽

10.1524/zkri.1989.189.14.109 ◽

1989 ◽

Vol 189 (1-4) ◽

Author(s):

O. Johnson ◽

D. W. Jones

Keyword(s):

Molecular Structure ◽

Crystal And Molecular Structure

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