ChemInform Abstract: Insertions of Small Molecules CO, CH3NC, SO2, and CS2into the Pd - Pd σ-Bond of Pd2Cl2(PMe2CH2PMe2)2. Crystal and Molecular Structure of Pd2(μ-CO)Cl2(PMe2CH2PMe2)2.

1986 ◽  
Vol 17 (20) ◽  
Author(s):  
M. L. KULLBERG ◽  
C. P. KUBIAK
2000 ◽  
Vol 55 (10) ◽  
pp. 895-900 ◽  
Author(s):  
Ulrich Jürgen Bildmann ◽  
Gerhard Müller

AbstractLithium Phosphides, Cyclopentadienides Treatment of 6,6-dimethylfulvene with LiPHPh in hexane/TMEDA (TMEDA = N,N,N′,N′- tetramethylethylenediamine) affords the monolithiated phosphinomethyl cyclopentadienide [Li(TMEDA)][PhHPCMe2C5H4] (1). Further reaction with LinBu in diethylether/TMEDA leads to the formation of the doubly lithiated phosphidomethyl cyclopentadienide [Li(TMEDA)]2[PhPCMe2C5H4] (2) whose crystal and molecular structure was determined (orthorhombic, space group P212121, a = 9.579(4), b = 12.788(2), c = 24.108(6) Å, Z = 4)


Sign in / Sign up

Export Citation Format

Share Document