Reaction of cyclopalladated compounds Part 16. Stepwise insertion of one, two, and three alkyne molecules into the palladium-carbon bond of a six-membered palladocycle. One-pot synthesis of spirocyclic compounds

1987 ◽  
Vol 6 (10) ◽  
pp. 2043-2053 ◽  
Author(s):  
Fida. Maassarani ◽  
Michel. Pfeffer ◽  
Guy. Le Borgne
Keyword(s):  
One Pot ◽  
Carbon Bond ◽  
One Pot Synthesis ◽  
Spirocyclic Compounds ◽  
Cyclopalladated Compounds

ChemInform Abstract: One-Pot Synthesis of α-Amino Acids Based on Free Radical-Mediated Carbon-Carbon Bond Formation.

ChemInform ◽  
2010 ◽  
Vol 30 (14) ◽  
pp. no-no
Author(s):  
Hideto Miyabe ◽  
Naoko Yoshioka ◽  
Masafumi Ueda ◽  
Takeaki Naito
Keyword(s):  
Amino Acids ◽  
Free Radical ◽  
Bond Formation ◽  
One Pot ◽  
Carbon Bond ◽  
One Pot Synthesis ◽  
Carbon Carbon Bond

One-Pot Synthesis of New Organometallic Compounds with Platinum-Carbon Bond

2020 ◽  
Vol 2020 (11-12) ◽  
pp. 1018-1026
Author(s):  
Alessandra Barbanente ◽  
Nicola Margiotta ◽  
Concetta Pacifico ◽  
Francesco P. Intini ◽  
Giovanni Natile
Keyword(s):  
Organometallic Compounds ◽  
One Pot ◽  
Carbon Bond ◽  
One Pot Synthesis

One-Pot Synthesis and Conformational Analysis of 6-Membered Cyclic Iodonium Salts

2020 ◽  
Author(s):  
Lucien Caspers ◽  
Julian Spils ◽  
Mattis Damrath ◽  
Enno Lork ◽  
Boris Nachtsheim
Keyword(s):  
Conformational Analysis ◽  
Bronsted Acids ◽  
One Pot ◽  
Benzyl Alcohols ◽  
Iodonium Salts ◽  
Efficient Approach ◽  
One Pot Synthesis ◽  
Diaryliodonium Salts

In this article we describe an efficient approach for the synthesis of cyclic diaryliodonium salts. The method is based on benzyl alcohols as starting materials and consists of an Friedel-Crafts-arylation/oxidation sequence. Besides a deep optimization, particluar focusing on the choice and ratios of the utilized Bronsted-acids and oxidants, we explore the substrate scope of this transformation. We also discuss an interesting isomerism of cyclic iodonium salts substituted with aliphatic substituents at the bridge head carbon. <br>

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