Preparation and condensation reactions of metal complexes of R2PNSO (R = methyl, phenyl) with potassium tert-butoxide: x-ray crystal structure of (CO)5Mo(Ph2PNSO)

1987 ◽  
Vol 6 (9) ◽  
pp. 1904-1909 ◽  
Author(s):  
Tristram. Chivers ◽  
Cees. Lensink ◽  
John F. Richardson
Polyhedron ◽  
1997 ◽  
Vol 16 (13) ◽  
pp. 2329-2333 ◽  
Author(s):  
Timothy E. Berridge ◽  
Hongli Chen ◽  
Thomas A. Hamor ◽  
Christopher J. Jones

1996 ◽  
Vol 51 (4) ◽  
pp. 501-505 ◽  
Author(s):  
Wolfgang Weigand ◽  
Michael Weishäupl ◽  
Christian Robl

Abstract The 1-alkyne-1-thiolates R-C ≡C-SLi [1a: R = C(CH3)3, 1b: R = C6H11 ] react with L2PtCl2 (L = PPh3, 1/2 dppe) and CpRu(PPh3)2Cl, respectively to give the complexes trans-(Ph3P)2Pt[S-C ≡C-C(CH3)3]2 (2a), cis-dppePt[S-C≡C-C(CH3)3]2 (2b), and CpRu(PPh3)2-(S-C ≡ C-R) [3a: R = C(CH3)3, 3b: R = C6H11]. 2a has been characterized by 31P CP/MAS NM R spectroscopy and its crystal structure determined by X-ray diffraction.


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