Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides

Bakthan Singaram; Thomas E. Cole; Herbert C. Brown

doi:10.1021/om00083a022

Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides

Organometallics ◽

10.1021/om00083a022 ◽

1984 ◽

Vol 3 (5) ◽

pp. 774-777 ◽

Cited By ~ 53

Author(s):

Bakthan Singaram ◽

Thomas E. Cole ◽

Herbert C. Brown

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Boronic Esters ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI METAL HYDRIDES. XIX. RAPID REACTION OF TRIALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM TRIALKYLBOROHYDRIDES, INCLUDING DE

Chemischer Informationsdienst ◽

10.1002/chin.198141232 ◽

1981 ◽

Vol 12 (41) ◽

Author(s):

H. C. BROWN ◽

J. L. HUBBARD ◽

B. SINGARAM

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI-METAL HYDRIDES. 21. RAPID REACTION OF DIALKYL- AND MONOALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM DIALKYL- AND MONOALKY

Chemischer Informationsdienst ◽

10.1002/chin.198219281 ◽

1982 ◽

Vol 13 (19) ◽

Author(s):

H. C. BROWN ◽

B. SINGARAM ◽

P. C. MATHEW

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Addition compounds of alkali metal hydrides. 30. Rapid reaction of trialkylboranes with lithium aluminum hydride. A novel and quantitative synthesis of lithium dialkylborohydrides

The Journal of Organic Chemistry ◽

10.1021/jo00381a003 ◽

1987 ◽

Vol 52 (5) ◽

pp. 728-730 ◽

Cited By ~ 14

Author(s):

Herbert C. Brown ◽

Milind V. Rangaishenvi ◽

Uday S. Racherla

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: Addition Compounds of Alkali-Metal Hydrides. Part 30. Rapid Reaction of Trialkylboranes with Lithium Aluminum Hydride. A Novel and Quantitative Synthesis of Lithium Dialkylborohydrides.

ChemInform ◽

10.1002/chin.198740219 ◽

1987 ◽

Vol 18 (40) ◽

Author(s):

H. C. BROWN ◽

M. V. RANGAISHENVI ◽

U. S. RACHERLA

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Addition compounds of alkali-metal hydrides. 21. Rapid reaction of dialkyl- and monoalkylboranes with lithium aluminum hydride in the presence of triethylenediamine. A facile and quantitative synthesis of lithium dialkyl- and monoalkylborohydrides

The Journal of Organic Chemistry ◽

10.1021/jo00335a044 ◽

1981 ◽

Vol 46 (22) ◽

pp. 4541-4544 ◽

Cited By ~ 11

Author(s):

Herbert C. Brown ◽

Bakthan Singaram ◽

Poonnoose C. Mathew

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

Download Full-text

ChemInform Abstract: RAPID REACTION OF TRIALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM TRIALKYLBOROHYDRIDES INCLUDING DERIVATIVES WITH EXCEPTIONALLY LARGE STERIC REQUIREMENT

Chemischer Informationsdienst ◽

10.1002/chin.198018257 ◽

1980 ◽

Vol 11 (18) ◽

Author(s):

H. C. BROWN ◽

J. L. HUBBARD ◽

B. SINGARAM

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: CHIRAL SYNTHESIS VIA ORGANOBORANES. 2. RAPID REACTION OF BORONIC ESTERS OF VERY HIGH OPTICAL PURITY WITH LITHIUM ALUMINUM HYDRIDE. FACILE REACTION OF ESSENTIALLY OPTICALLY PURE BORINIC ESTERS WITH LITHIUM MONOETHOXYALUMINOHYDRIDE. A N

Chemischer Informationsdienst ◽

10.1002/chin.198521284 ◽

1985 ◽

Vol 16 (21) ◽

Author(s):

H. C. BROWN ◽

B. SINGARAM ◽

T. E. COLE

Keyword(s):

Lithium Aluminum Hydride ◽

Optical Purity ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Chiral Synthesis ◽

High Optical Purity ◽

Boronic Esters ◽

Rapid Reaction ◽

Optically Pure ◽

Very High

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Chiral synthesis via organoboranes. 2. Rapid reaction of boronic esters of very high optical purity with lithium aluminum hydride. Facile reaction of essentially optically pure borinic esters with lithium monoethoxyaluminohydride. A novel and quantitative synthesis of lithium monoalkyl- and dialkylborohydrides of essentially 100% optical purity

Journal of the American Chemical Society ◽

10.1021/ja00288a031 ◽

1985 ◽

Vol 107 (2) ◽

pp. 460-464 ◽

Cited By ~ 26

Author(s):

Herbert C. Brown ◽

Bakthan Singaram ◽

Thomas E. Cole

Keyword(s):

Lithium Aluminum Hydride ◽

Optical Purity ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Chiral Synthesis ◽

High Optical Purity ◽

Boronic Esters ◽

Quantitative Synthesis ◽

Optically Pure ◽

Very High

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Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylenediamine. Facile and quantitative synthesis of lithium trialkylborohydrides including derivatives with exceptionally large steric requirements

The Journal of Organic Chemistry ◽

10.1021/jo00394a067 ◽

1979 ◽

Vol 44 (26) ◽

pp. 5004-5005 ◽

Cited By ~ 10

Author(s):

Herbert C. Brown ◽

John L. Hubbard ◽

Bakthan Singaram

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Reduction of Halophosphines with Lithium Aluminum Hydride or Other Metal Hydrides

Category 5, Compounds with One Saturated Carbon Heteroatom Bond ◽

10.1055/sos-sd-042-00093 ◽

2009 ◽

pp. 1

Author(s):

E. Hey-Hawkins ◽

A. A. Karasik

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum

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