Addition compounds of alkali-metal hydrides. 21. Rapid reaction of dialkyl- and monoalkylboranes with lithium aluminum hydride in the presence of triethylenediamine. A facile and quantitative synthesis of lithium dialkyl- and monoalkylborohydrides

Herbert C. Brown; Bakthan Singaram; Poonnoose C. Mathew

doi:10.1021/jo00335a044

Addition compounds of alkali-metal hydrides. 21. Rapid reaction of dialkyl- and monoalkylboranes with lithium aluminum hydride in the presence of triethylenediamine. A facile and quantitative synthesis of lithium dialkyl- and monoalkylborohydrides

The Journal of Organic Chemistry ◽

10.1021/jo00335a044 ◽

1981 ◽

Vol 46 (22) ◽

pp. 4541-4544 ◽

Cited By ~ 11

Author(s):

Herbert C. Brown ◽

Bakthan Singaram ◽

Poonnoose C. Mathew

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Addition compounds of alkali-metal hydrides. 25. Rapid reaction of boronic esters and acids with lithium aluminum hydride. A novel and quantitative synthesis of lithium monoorganylborohydrides

Organometallics ◽

10.1021/om00083a022 ◽

1984 ◽

Vol 3 (5) ◽

pp. 774-777 ◽

Cited By ~ 53

Author(s):

Bakthan Singaram ◽

Thomas E. Cole ◽

Herbert C. Brown

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Boronic Esters ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI METAL HYDRIDES. XIX. RAPID REACTION OF TRIALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM TRIALKYLBOROHYDRIDES, INCLUDING DE

Chemischer Informationsdienst ◽

10.1002/chin.198141232 ◽

1981 ◽

Vol 12 (41) ◽

Author(s):

H. C. BROWN ◽

J. L. HUBBARD ◽

B. SINGARAM

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: ADDITION COMPOUNDS OF ALKALI-METAL HYDRIDES. 21. RAPID REACTION OF DIALKYL- AND MONOALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. A FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM DIALKYL- AND MONOALKY

Chemischer Informationsdienst ◽

10.1002/chin.198219281 ◽

1982 ◽

Vol 13 (19) ◽

Author(s):

H. C. BROWN ◽

B. SINGARAM ◽

P. C. MATHEW

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Addition compounds of alkali metal hydrides. 30. Rapid reaction of trialkylboranes with lithium aluminum hydride. A novel and quantitative synthesis of lithium dialkylborohydrides

The Journal of Organic Chemistry ◽

10.1021/jo00381a003 ◽

1987 ◽

Vol 52 (5) ◽

pp. 728-730 ◽

Cited By ~ 14

Author(s):

Herbert C. Brown ◽

Milind V. Rangaishenvi ◽

Uday S. Racherla

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: Addition Compounds of Alkali-Metal Hydrides. Part 30. Rapid Reaction of Trialkylboranes with Lithium Aluminum Hydride. A Novel and Quantitative Synthesis of Lithium Dialkylborohydrides.

ChemInform ◽

10.1002/chin.198740219 ◽

1987 ◽

Vol 18 (40) ◽

Author(s):

H. C. BROWN ◽

M. V. RANGAISHENVI ◽

U. S. RACHERLA

Keyword(s):

Alkali Metal ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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ChemInform Abstract: RAPID REACTION OF TRIALKYLBORANES WITH LITHIUM ALUMINUM HYDRIDE IN THE PRESENCE OF TRIETHYLENEDIAMINE. FACILE AND QUANTITATIVE SYNTHESIS OF LITHIUM TRIALKYLBOROHYDRIDES INCLUDING DERIVATIVES WITH EXCEPTIONALLY LARGE STERIC REQUIREMENT

Chemischer Informationsdienst ◽

10.1002/chin.198018257 ◽

1980 ◽

Vol 11 (18) ◽

Author(s):

H. C. BROWN ◽

J. L. HUBBARD ◽

B. SINGARAM

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Rapid reaction of trialkylboranes with lithium aluminum hydride in the presence of triethylenediamine. Facile and quantitative synthesis of lithium trialkylborohydrides including derivatives with exceptionally large steric requirements

The Journal of Organic Chemistry ◽

10.1021/jo00394a067 ◽

1979 ◽

Vol 44 (26) ◽

pp. 5004-5005 ◽

Cited By ~ 10

Author(s):

Herbert C. Brown ◽

John L. Hubbard ◽

Bakthan Singaram

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Lithium Aluminum ◽

Quantitative Synthesis ◽

Rapid Reaction

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Reduction of Halophosphines with Lithium Aluminum Hydride or Other Metal Hydrides

Category 5, Compounds with One Saturated Carbon Heteroatom Bond ◽

10.1055/sos-sd-042-00093 ◽

2009 ◽

pp. 1

Author(s):

E. Hey-Hawkins ◽

A. A. Karasik

Keyword(s):

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum

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Conformational analysis. XXI. Reduction with metal hydrides. XX. Stereochemistry of reduction of ortho esters with lithium aluminum hydride and mixed hydrides

Journal of the American Chemical Society ◽

10.1021/ja00713a021 ◽

1970 ◽

Vol 92 (10) ◽

pp. 3045-3050 ◽

Cited By ~ 15

Author(s):

Ernest L. Eliel ◽

Franz W. Nader

Keyword(s):

Conformational Analysis ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Lithium Aluminum ◽

Ortho Esters

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Reductions with Metal Hydrides. XVIII. Reductions of Ketones with Lithium Aluminum Hydride—Aluminum Chloride and Hydride Transfer from the Resulting Alcohol Complexes1

The Journal of Organic Chemistry ◽

10.1021/jo01022a049 ◽

1965 ◽

Vol 30 (11) ◽

pp. 3809-3814 ◽

Cited By ~ 29

Author(s):

Ernest L. Eliel ◽

D. Nasipuri

Keyword(s):

Aluminum Chloride ◽

Lithium Aluminum Hydride ◽

Aluminum Hydride ◽

Metal Hydrides ◽

Hydride Transfer ◽

Lithium Aluminum

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