Preparation and properties of Ge(CF3)3 adducts of transition metal carbonyls: x-ray structure of (CF3)3GeMn(CO)5

1983 ◽  
Vol 2 (2) ◽  
pp. 263-267 ◽  
Author(s):  
David J. Brauer ◽  
Reint Eujen
Keyword(s):  
Transition Metal ◽  
Metal Carbonyls ◽  
X Ray ◽  
Transition Metal Carbonyls

Über die Reaktion von C(NMe2)4 mit zweikernigen Übergangsmetallcarbonylen; Kristallstrukturen von [C(NMe2)3][Mn(CO)5] und [C(NMe2)3][Co(CO)4] / On the Reaction of C(NMe2)4 with Binuclear Transition Metal Carbonyls: Crystal Structures of [C(NMe2)3][Mn(CO)5] and [C(NMe2)3][Co(CO)4]

1991 ◽  
Vol 46 (3) ◽  
pp. 297-302 ◽  
Author(s):  
Wolfgang Petz ◽  
Frank Weller
Keyword(s):  
Transition Metal ◽  
Crystal Structures ◽  
Structure Determination ◽  
Metal Carbonyls ◽  
Space Group ◽  
X Ray ◽  
Transition Metal Carbonyls ◽  
C Nmr

The reactions of C(NMe2)4 (1) with Mn2(CO)10 or Co2(CO)8 in THF yield[C(NMe2)3][Co(CO)4] (3) and [C(NMe2)3][Mn(CO)5] (4), respectively. The compounds Co(CO)4NMe2 (5) and Mn(CO)5NMe2 (6) could not be found. With CH2Cl2 4 is quantitatively converted into [C(NMe2)3][Mn(CO)4Cl2] (7) as shown by IR and 13C NMR investigations. 3 and 4 were characterized by an X-ray structure determination. 3: Space group Pnma, Z = 4, a = 7.435(2), b = 10.79(2), c = 20.299(5)Å. 4: Space group C2/c, Z = 4, a = 11.378(2), b = 10.165(1), c = 14.533(1) Å; β = 103.37(1)°. The compounds form independent ions with no bonding interactions between cation and anion; the central CN3 unit of the [C(NMe2)3]+ cation in 3 and 4 is disordered.

Observation of Carbon–Carbon Coupling Reaction in Neutral Transition-Metal Carbonyls

2021 ◽  
Vol 12 (3) ◽  
pp. 1012-1017
Author(s):  
Chong Wang ◽  
Qinming Li ◽  
Xiangtao Kong ◽  
Huijun Zheng ◽  
Tiantong Wang ◽  
...  
Keyword(s):  
Transition Metal ◽  
Coupling Reaction ◽  
Metal Carbonyls ◽  
Transition Metal Carbonyls

17O NMR spectroscopy of transition metal carbonyls

1979 ◽  
Vol 178 (1) ◽  
pp. 171-175 ◽  
Author(s):  
S. Aime ◽  
L. Milone ◽  
D. Osella ◽  
G.E. Hawkes ◽  
E.W. Randall
Keyword(s):  
Nmr Spectroscopy ◽  
Transition Metal ◽  
Metal Carbonyls ◽  
17O Nmr ◽  
Transition Metal Carbonyls ◽  
17O Nmr Spectroscopy
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