Alkylidyne (carbaborane) complexes of the Group 6 metals. 9. The closo to hyper-closo transformations in a tungstacarborane cage system: crystal structure of [NEt4][W2(.mu.-CC6H4Me-4)(CO)2(.eta.5-7,8-Me2-7,8-C2B9H9)[.eta.6-7,8-Me2-7,8-C2B9H8-10-(CH2C6H4Me-4)]]

Nicholas Carr; Donald F. Mullica; Eric L. Sappenfield; F. Gordon A. Stone

doi:10.1021/om00059a037

Alkylidyne (carbaborane) complexes of the Group 6 metals. 9. The closo to hyper-closo transformations in a tungstacarborane cage system: crystal structure of [NEt4][W2(.mu.-CC6H4Me-4)(CO)2(.eta.5-7,8-Me2-7,8-C2B9H9)[.eta.6-7,8-Me2-7,8-C2B9H8-10-(CH2C6H4Me-4)]]

Organometallics ◽

10.1021/om00059a037 ◽

1992 ◽

Vol 11 (11) ◽

pp. 3697-3704 ◽

Cited By ~ 18

Author(s):

Nicholas Carr ◽

Donald F. Mullica ◽

Eric L. Sappenfield ◽

F. Gordon A. Stone

Keyword(s):

Crystal Structure ◽

Cage System ◽

Group 6

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ChemInform Abstract: CHEMISTRY OF THE METAL CARBONYLS. PART 82. SYNTHESIS OF COMPLEXES WITH BONDS BETWEEN RHODIUM AND THE SUB-GROUP 6 METALS: X-RAY CRYSTAL STRUCTURE OF 2-(1′-6′-η-BENZENE)-DI-μ-CARBONYL-1,2-DICARBONYL-1-(1′-5′-η-PENTAMET# HYLCYCLOPENTADIE

Chemischer Informationsdienst ◽

10.1002/chin.198324327 ◽

1983 ◽

Vol 14 (24) ◽

Author(s):

R. D. BARR ◽

M. GREEN ◽

K. MARSDEN ◽

F. G. A. STONE ◽

P. WOODWARD

Keyword(s):

Crystal Structure ◽

Metal Carbonyls ◽

X Ray ◽

Group 6

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ChemInform Abstract: Heteronuclear Complexes Containing Group 6 Transition Metals; Chemical, Spectroscopic, and Theoretical Studies on Some Binuclear Complexes and the X-Ray Crystal Structure Determination of (WNi(CO)3(PPh3)2(η5-C5H5)).

ChemInform ◽

10.1002/chin.198809312 ◽

1988 ◽

Vol 19 (9) ◽

Author(s):

L. CARLTON ◽

W. E. LINDSELL ◽

K. J. MCCULLOUGH ◽

P. N. PRESTON

Keyword(s):

Crystal Structure ◽

Transition Metals ◽

Structure Determination ◽

Crystal Structure Determination ◽

Theoretical Studies ◽

Binuclear Complexes ◽

X Ray ◽

Heteronuclear Complexes ◽

Group 6

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Synthesis and coordination chemistry of neutral phospha(iii)guanidines. Formation of 1-aza-3-phospha-4-metallacyclobut-1-ene rings at group 6 metalsElectronic supplementary information (ESI) available: an ORTEP representation and bond lengths and angles for 3a; crystal structure and refinement data, bond lengths and angles and an ORTEP representation of the molecular structure of Mo(CO)4(pip)2. See http://www.rsc.org/suppdata/dt/b3/b302554c/

Dalton Transactions ◽

10.1039/b302554c ◽

2003 ◽

pp. 2573 ◽

Cited By ~ 28

Author(s):

Joanna Grundy ◽

Martyn P. Coles ◽

Peter B. Hitchcock

Keyword(s):

Molecular Structure ◽

Crystal Structure ◽

Coordination Chemistry ◽

Supplementary Information ◽

Bond Lengths ◽

Group 6

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Heterometallic cubane-type clusters containing group 13 and 16 elements

Pure and Applied Chemistry ◽

10.1351/pac-con-11-10-17 ◽

2012 ◽

Vol 84 (11) ◽

pp. 2233-2241 ◽

Cited By ~ 4

Author(s):

K. Geetharani ◽

Shubhankar Kumar Bose ◽

Sundargopal Ghosh

Keyword(s):

Crystal Structure ◽

Transition Metal ◽

Spectroscopic Study ◽

Carbonyl Compounds ◽

Metal Carbonyl ◽

Group 13 ◽

Metal Metal ◽

Valence Electrons ◽

Group 6 ◽

Metal Bonds

Heterometallic cubane-type clusters were synthesized from the reaction of group 6 and 8 metallaboranes using transition-metal carbonyl compounds. Structural and spectroscopic study revealed the existence of novel “capped-cubane” geometry. In addition, the crystal structure of these clusters distinctly confirms the presence of boride unit as one of the vertices. These clusters possess 60 cluster valence electrons (cve) and six metal–metal bonds. A plausible pathway for the formation of ruthenium-capped cubane has been described.

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X-ray crystal structure analysis of the heptacyclic molecule C28H39O4Br containing a novel cage system

Acta Crystallographica Section B ◽

10.1107/s0567740874006637 ◽

1974 ◽

Vol 30 (9) ◽

pp. 2151-2156

Author(s):

J. A. Turner ◽

R. S. McEwen

Keyword(s):

Crystal Structure ◽

Structure Analysis ◽

Crystal Structure Analysis ◽

X Ray ◽

Cage System

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ChemInform Abstract: Comparative Reactivities of Anionic Group 6 Alkyl, Silyl, and Stannyl Pentacarbonyl Metalates Toward Carbon Dioxide and Sulfur Dioxide. Crystal Structure of (PPN) (W(CO)5Si(CH3)3).

ChemInform ◽

10.1002/chin.198911254 ◽

1989 ◽

Vol 20 (11) ◽

Author(s):

D. J. DARENSBOURG ◽

C. G. BAUCH ◽

J. H. REIBENSPIES ◽

A. L. RHEINGOLD

Keyword(s):

Crystal Structure ◽

Carbon Dioxide ◽

Sulfur Dioxide ◽

Anionic Group ◽

Group 6

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ChemInform Abstract: Bimetallic Systems. Part 17. Synthesis of Group 6 Metal(0)-Copper(I)-Silver(I), or -Gold(I) Complexes with Two Ph2PCH2PPh2 (dppm) Bridging Ligands: Crystal Structure of ((OC)2W(μ-CO)(μ-dppm)2(μ-Cl)Cu)·CH2Cl2.

ChemInform ◽

10.1002/chin.198731285 ◽

1987 ◽

Vol 18 (31) ◽

Author(s):

A. BLAGG ◽

B. L. SHAW ◽

M. THORNTON-PETT

Keyword(s):

Crystal Structure ◽

Bridging Ligands ◽

Bimetallic Systems ◽

Group 6

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Reactions of [Ru{C6H4(NH)2-1,2}(PPh3)3] with Group 6 metal carbonyls. Crystal structure and reactivity with diphosphines of the linear heterotrinuclear complex [Ru2Mo{µ-C6H4(NH)2-1,2}2(CO)6(PPh3)2]

Journal of the Chemical Society Dalton Transactions ◽

10.1039/dt9930003287 ◽

1993 ◽

pp. 3287-3292 ◽

Cited By ~ 4

Author(s):

Adela Anillo ◽

Santiago García-Granda ◽

Ricardo Obeso-Rosete ◽

Juan Manuel Rubio-González

Keyword(s):

Crystal Structure ◽

Metal Carbonyls ◽

Group 6 ◽

Heterotrinuclear Complex

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Comparative reactivities of anionic group 6 alkyl, silyl, and stannyl pentacarbonyl metalates toward carbon dioxide and sulfur dioxide. Crystal structure of bis(triphenylphosphine)nitrogen(1+) pentacarbonyl(trimethylsilyl)tungstate(1-)

Inorganic Chemistry ◽

10.1021/ic00296a022 ◽

1988 ◽

Vol 27 (23) ◽

pp. 4203-4207 ◽

Cited By ~ 12

Author(s):

Donald J. Darensbourg ◽

Christopher G. Bauch ◽

Joseph H. Reibenspies ◽

Arnold L. Rheingold

Keyword(s):

Crystal Structure ◽

Carbon Dioxide ◽

Sulfur Dioxide ◽

Anionic Group ◽

Group 6

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Preparation, Mechanism, and Structural Study of Group 6 Transition Metal 2-Substituted η3-Butadienyl Complexes: Crystal Structure of [WCl(CO)2{η3-CH2C(COSBun)CCH2}(1,10-phenanthroline)]

Organometallics ◽

10.1021/om980521j ◽

1998 ◽

Vol 17 (24) ◽

pp. 5347-5352 ◽

Cited By ~ 8

Author(s):

Annabelle G. W. Hodson ◽

Gráinne Conole

Keyword(s):

Crystal Structure ◽

Transition Metal ◽

Structural Study ◽

Group 6

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