Synthesis and Molecular Structure of the Trinuclear Mixed-Metal Complex [{(Me2NCH2CH2CH2)2Cr(.mu.-Cl)2}2Mg] and of the Tetranuclear Grignard Reagent [(Me2NCH2CH2CH2)Mg2Cl3(THF)2]2

1994 ◽  
Vol 13 (10) ◽  
pp. 4105-4108 ◽  
Author(s):  
Umberto Casellato ◽  
Franco Ossola
Keyword(s):  
Molecular Structure ◽  
Metal Complex ◽  
Grignard Reagent ◽  
Mixed Metal

[4-tBu-2,6-{P(O)(OiPr)2}2C6H2Sn(PPh3)Cr(CO)5]ClO4 – a salt containing a cationic triphenylphosphane-stabilized organostannylene transition metal complex

2015 ◽  
Vol 38 (5-6) ◽  
Author(s):  
Michael Wagner ◽  
Thomas Zöller ◽  
Christina Dietz ◽  
Klaus Jurkschat
Keyword(s):  
Molecular Structure ◽  
Transition Metal ◽  
Metal Complex ◽  
Transition Metal Complex

AbstractThe isolation and molecular structure of bis(di-

Synthese und Eigenschaften einiger Silylethinylsilane; Molekülstruktur von Tetrakis(trimethylsilylethinyl)silan / Synthesis and Properties of Some Silylethynylsilane; Molecular Structure of Tetrakis(trimethylsilylethynyl)silane

1988 ◽  
Vol 43 (1) ◽  
pp. 49-52 ◽  
Author(s):  
Hubert Schmidbaur ◽  
Jan Ebenhöch
Keyword(s):  
Molecular Structure ◽  
Crystal Structure ◽  
Single Crystal ◽  
Silicon Atom ◽  
Grignard Reagent ◽  
X Ray Diffraction ◽  
Tetrahedral Geometry ◽  
X Ray ◽  
Nmr Data

Abstract Trimethylsilylethine (1) has been prepared from C2H2, sodium and Me3SiCl in anisole. The product can be converted into a Grignard reagent Me3SiC≡CMgCl using iPrMgCl. This reagent yields the compounds Me3SiC≡CSiH3, (Me3SiC≡C)2SiH2, (Me3SiC≡C)3SiH, and (Me3SiC≡C)4Si (2-5) when treated with equivalent amounts of H3SiBr, H2SiBr2, HSiCl3, or SiCl4. respectively. The new silanes have been characterized by NMR data. The crystal structure of (Me3SiC≡C)4Si has been determined by single crystal X-ray diffraction. It shows the expected tetrahedral geometry at he central silicon atom with four linear SiC≡CSi linkages.

Synthesis, characterization, and molecular structure of the first metal complex containing thallium chloride as a ligand. A novel carrier of thallium(I)

1992 ◽  
Vol 31 (20) ◽  
pp. 4036-4037 ◽  
Author(s):  
Claudio Bianchini ◽  
Dante Masi ◽  
Klaus Linn ◽  
Carlo Mealli ◽  
Maurizio Peruzzini ◽  
...  
Keyword(s):  
Molecular Structure ◽  
Metal Complex ◽  
Thallium Chloride
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