scholarly journals Ruthenium Catalyzed C−C Bond Formation via Transfer Hydrogenation: Branch-Selective Reductive Coupling of Allenes to Paraformaldehyde and Higher Aldehydes

2008 ◽  
Vol 10 (13) ◽  
pp. 2705-2708 ◽  
Author(s):  
Ming-Yu Ngai ◽  
Eduardas Skucas ◽  
Michael J. Krische
Keyword(s):  
Bond Formation ◽  
Transfer Hydrogenation ◽  
Reductive Coupling

Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Short Review ◽  
Reductive Coupling ◽  
Recent Developments ◽  
Molecular Complexity ◽  
Metal Catalyzed ◽  
Coupling Processes ◽  
Coupling Strategies

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook

Carbon-carbon bond formation in the reductive coupling of nitriles at a multiply bonded dirhenium center

1988 ◽  
Vol 27 (18) ◽  
pp. 3066-3067 ◽  
Author(s):  
David Esjornson ◽  
Phillip E. Fanwick ◽  
Richard A. Walton
Keyword(s):  
Bond Formation ◽  
Reductive Coupling ◽  
Carbon Bond ◽  
Carbon Carbon Bond ◽  
Multiply Bonded
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