From Hydrogenation to Transfer Hydrogenation to Hydrogen Auto-Transfer in Enantioselective Metal-Catalyzed Carbonyl Reductive Coupling: Past, Present, and Future

ACS Catalysis ◽  
2021 ◽  
pp. 5572-5585
Author(s):  
Catherine Gazolla Santana ◽  
Michael J. Krische
Keyword(s):  
Transfer Hydrogenation ◽  
Reductive Coupling ◽  
Metal Catalyzed

scholarly journals Metal-catalyzed reductive coupling of olefin-derived nucleophiles: Reinventing carbonyl addition

Science ◽  
2016 ◽  
Vol 354 (6310) ◽  
pp. aah5133 ◽  
Author(s):  
Khoa D. Nguyen ◽  
Boyoung Y. Park ◽  
Tom Luong ◽  
Hiroki Sato ◽  
Victoria J. Garza ◽  
...  
Keyword(s):  
Reductive Coupling ◽  
Carbonyl Addition ◽  
Metal Catalyzed

Recent Developments in C–C Bond Formation Using Catalytic Reductive Coupling Strategies

Synthesis ◽  
2020 ◽  
Vol 52 (18) ◽  
pp. 2623-2638
Author(s):  
Joshua D. Sieber ◽  
Toolika Agrawal
Keyword(s):  
Bond Formation ◽  
Cross Coupling ◽  
Short Review ◽  
Reductive Coupling ◽  
Recent Developments ◽  
Molecular Complexity ◽  
Metal Catalyzed ◽  
Coupling Processes ◽  
Coupling Strategies

Metal-catalyzed reductive coupling processes have emerged as a powerful methodology for the introduction of molecular complexity from simple starting materials. These methods allow for an orthogonal approach to that of redox-neutral strategies for the formation of C–C bonds by enabling cross-coupling of starting materials not applicable to redox-neutral chemistry. This short review summarizes the most recent developments in the area of metal-catalyzed reductive coupling utilizing catalyst turnover by a stoichiometric reductant that becomes incorporated in the final product.1 Introduction2 Ni Catalysis3 Cu Catalysis4 Ru, Rh, and Ir Catalysis4.1 Alkenes4.2 1,3-Dienes4.3 Allenes4.4 Alkynes4.5 Enynes5 Fe, Co, and Mn Catalysis6 Conclusion and Outlook

Ligand Effect in Alkali‐Metal‐Catalyzed Transfer Hydrogenation of Ketones

2019 ◽  
Vol 25 (50) ◽  
pp. 11734-11744 ◽  
Author(s):  
Iryna D. Alshakova ◽  
Hayden C. Foy ◽  
Travis Dudding ◽  
Georgii I. Nikonov
Keyword(s):  
Alkali Metal ◽  
Transfer Hydrogenation ◽  
Ligand Effect ◽  
Metal Catalyzed

Feedstock Reagents in Metal‐Catalyzed Carbonyl Reductive Coupling: Minimizing Preactivation for Efficiency in Target‐Oriented Synthesis

2019 ◽  
Vol 131 (40) ◽  
pp. 14193-14202 ◽  
Author(s):  
Rosalie S. Doerksen ◽  
Cole C. Meyer ◽  
Michael J. Krische
Keyword(s):  
Reductive Coupling ◽  
Metal Catalyzed
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