Switching between Reaction Pathways by an Alcohol Cosolvent Effect: SmI2–Ethylene Glycol vs SmI2–H2O Mediated Synthesis of Uracils

2014 ◽  
Vol 16 (21) ◽  
pp. 5694-5697 ◽  
Author(s):  
Michal Szostak ◽  
Malcolm Spain ◽  
Brice Sautier ◽  
David J. Procter
Keyword(s):  
Ethylene Glycol ◽  
Reaction Pathways

scholarly journals Microwave-assisted lignin liquefaction in hydrazine and ethylene glycol: Reaction pathways via response surface methodology

2021 ◽  
Vol 27 ◽  
pp. e00245
Author(s):  
Divine B. Nde ◽  
Mohamad Barekati-Goudarzi ◽  
Pranjali D. Muley ◽  
Lavrent Khachatryan ◽  
Dorin Boldor
Keyword(s):  
Response Surface Methodology ◽  
Ethylene Glycol ◽  
Response Surface ◽  
Reaction Pathways ◽  
Microwave Assisted

Catalytic conversion of cellulose for efficient ethylene glycol production and insights into the reaction pathways

RSC Advances ◽  
2016 ◽  
Vol 6 (81) ◽  
pp. 77499-77506 ◽  
Author(s):  
Kai Zhang ◽  
Shubin Wu ◽  
He Yang ◽  
Huimin Yin ◽  
Gang Li
Keyword(s):  
Ethylene Glycol ◽  
Model Compound ◽  
Catalytic Conversion ◽  
Reaction Pathways ◽  
Hydrothermal Conversion ◽  
One Pot ◽  
Highly Active ◽  
Mixed Catalyst

A highly active mixed catalyst consisting of PTA and Ru/AC was used for one-pot hydrothermal conversion of cellulose for EG production, and insights into the reaction pathways were obtained with the aid of cellobiose as a model compound.

Catalytic Hydrogenolysis of Biomass-derived Polyhydric Compounds to C2–C3 Small- Molecule Polyols: A Review

2019 ◽  
Vol 23 (20) ◽  
pp. 2180-2189 ◽  
Author(s):  
Chiliu Cai ◽  
Changhui Zhu ◽  
Haiyong Wang ◽  
Haosheng Xin ◽  
Zhongxun Xiu ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Small Molecule ◽  
Petrochemical Industry ◽  
State Of The Art ◽  
Biomass Energy ◽  
Reaction Pathways ◽  
Technical Aspects ◽  
Biodiesel Synthesis ◽  
Catalytic Hydrogenolysis ◽  
Selective Hydrogenolysis

Biomass energy has attracted much attention because of its clean and renewable characteristics. At present, C2–C3 polyols such as glycerol, 1,2-propanediol, and ethylene glycol, widely used as platforms for downstream chemicals or directly used as chemicals in diversified industries, mainly depend on the petrochemical industry. In terms of the feedstock for C2–C3 polyol production, the C3-derived glycerol is a side product during biodiesel synthesis, whereas the C5-derived xylitol and C6-derived sorbitol can be mainly obtained by hydrolysis–hydrogenation of hemicellulose and cellulose from lignocellulosic biomass, respectively. In this review, we summarize the catalysts and catalysis for selective hydrogenolysis of these polyhydric compounds to C2–C3 polyols and introduce the reaction pathways for the target polyol formation based on the C3, C5, and C6 polyhydric alcohol hydrogenolysis. Finally, state-of-the-art technologies are described and the remaining challenges and further prospects are presented in view of the technical aspects.

ChemInform Abstract: Switching Between Reaction Pathways by an Alcohol Cosolvent Effect: SmI2-Ethylene Glycol vs SmI2-H2O Mediated Synthesis of Uracils.

ChemInform ◽  
2015 ◽  
Vol 46 (15) ◽  
pp. no-no
Author(s):  
Michal Szostak ◽  
Malcolm Spain ◽  
Brice Sautier ◽  
David J. Procter
Keyword(s):  
Ethylene Glycol ◽  
Reaction Pathways

Theoretical and Experimental Studies of C–C versus C–O Bond Scission of Ethylene Glycol Reaction Pathways via Metal-Modified Molybdenum Carbides

ACS Catalysis ◽  
2014 ◽  
Vol 4 (5) ◽  
pp. 1409-1418 ◽  
Author(s):  
Weiting Yu ◽  
Michael Salciccioli ◽  
Ke Xiong ◽  
Mark A. Barteau ◽  
Dionisios G. Vlachos ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Experimental Studies ◽  
Reaction Pathways ◽  
Molybdenum Carbides ◽  
Bond Scission

PIEZOELECTRIC PROPERTIES OF POLY(3-HYDROXYBUTYRATE-CO-3-HEDROXYBUTYRATE)-CO-POLY(ETHYLENE GLYCOL) PRODUCED BY CONTROLLED MICROBIOLOGICAL BIOSYNTHESIS

2019 ◽  
Vol 10 (10) ◽  
Author(s):  
Anton Bonartsev ◽  
Vera Voinova ◽  
Elizaveta Akoulina ◽  
Andrey Dudun ◽  
Irina Zharkova ◽  
...  
Keyword(s):  
Ethylene Glycol ◽  
Piezoelectric Properties ◽  
Poly Ethylene Glycol ◽  
Poly Ethylene
Sign in / Sign up

Export Citation Format

Share Document