Diffusion Controlled Hydrogen Atom Abstraction from Tertiary Amines by the Benzyloxyl Radical. The Importance of C−H/N Hydrogen Bonding

2011 ◽  
Vol 13 (2) ◽  
pp. 260-263 ◽  
Author(s):  
Michela Salamone ◽  
Gloria Anastasi ◽  
Massimo Bietti ◽  
Gino A. DiLabio
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Atom ◽  
Hydrogen Atom Abstraction ◽  
Tertiary Amines ◽  
Diffusion Controlled

Hydrogen atom abstraction reactions independent of C–H bond dissociation energies of organic substrates in water: significance of oxidant–substrate adduct formation

2014 ◽  
Vol 5 (4) ◽  
pp. 1429-1436 ◽  
Author(s):  
Tomoya Ishizuka ◽  
Shingo Ohzu ◽  
Hiroaki Kotani ◽  
Yoshihito Shiota ◽  
Kazunari Yoshizawa ◽  
...  
Keyword(s):  
Hydrogen Bonding ◽  
Hydrogen Atom ◽  
Transition States ◽  
Adduct Formation ◽  
Hydrogen Atom Abstraction ◽  
Organic Substrates ◽  
Bond Dissociation Energies ◽  
Bond Dissociation ◽  
Dissociation Energies ◽  
Oxo Complexes

Adduct formation between Ru(iv)–oxo complexes and substrates with hydrogen bonding affords condensed transition states for substrate oxidations in water.

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