scholarly journals Nickel-Catalyzed Cycloaddition of Unsaturated Hydrocarbons and Carbonyl Compounds

2005 ◽  
Vol 7 (21) ◽  
pp. 4785-4785 ◽  
Author(s):  
Thomas N. Tekavec ◽  
Janis Louie
Keyword(s):  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons

Highly selective oxidation of unsaturated hydrocarbons to carbonyl compounds by two-phase catalysis

Tetrahedron ◽  
2016 ◽  
Vol 72 (42) ◽  
pp. 6705-6710 ◽  
Author(s):  
Chun Mi ◽  
Lu Li ◽  
Xiang-Guang Meng ◽  
Ren-Qiang Yang ◽  
Xiao-Hong Liao
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons ◽  
Two Phase

Nickel-Catalyzed Cycloaddition of Unsaturated Hydrocarbons and Carbonyl Compounds

2005 ◽  
Vol 7 (18) ◽  
pp. 4037-4039 ◽  
Author(s):  
Thomas N. Tekevac ◽  
Janis Louie
Keyword(s):  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons

Transition-Metal-Catalyzed Asymmetric Allylation of Carbonyl Compounds with Unsaturated Hydrocarbons

Synthesis ◽  
2017 ◽  
Vol 50 (05) ◽  
pp. 956-967 ◽  
Author(s):  
Liu-Zhu Gong ◽  
Pu-Sheng Wang ◽  
Meng-Lan Shen
Keyword(s):  
Transition Metal ◽  
Carbonyl Compounds ◽  
Building Blocks ◽  
Asymmetric Allylation ◽  
Unsaturated Hydrocarbons ◽  
Homoallylic Alcohols ◽  
Carbon Carbon Bonds ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Direct Use

The asymmetric allylation of carbonyl compounds is an important process for the formation of carbon–carbon bonds, generating optically active homoallylic alcohols that are versatile building blocks with widespread applications in organic synthesis. The use of readily available unsaturated hydrocarbons as allylating reagents in the transition-metal-catalyzed asymmetric allylation has received increasing interest as either a step- or an atom-economy alternative. This review summarizes transition-metal-catalyzed enantioselective allylations on the basis of the ‘indirect’ and ‘direct’ use of simple unsaturated hydrocarbons (include dienes, allenes, alkynes, and alkenes) as allylating reagents, with emphasis on highlighting conceptually novel reactions.1 Introduction2 ‘Indirect’ Use of Unsaturated Hydrocarbons in Asymmetric Allylation of Carbonyl Compounds2.1 Enantioselective Allylation with 1,3-Dienes2.2 Enantioselective Allylation with Allenes2.3 Enantioselective Allylation with Alkenes3 ‘Direct’ Use of Unsaturated Hydrocarbons in Asymmetric Allylation of Carbonyl Compounds3.1 Enantioselective Allylation with 1,3-Dienes3.2 Enantioselective Allylation with Allenes3.3 Enantioselective Allylation with Alkynes3.4 Enantioselective Allylation with Alkenes4 Conclusions

Silicon Assisted Sulfuration: Tetrachlorosilane-Sodium Sulfide-A New Potent Thionating Reagent for Carbonyl Compounds

2007 ◽  
Author(s):  
T. A. Salama ◽  
S. S. Elmorsy ◽  
A. M. Khalil ◽  
M. A. Ismail ◽  
A. S. El-Ahl
Keyword(s):  
Carbonyl Compounds ◽  
Sodium Sulfide

A FACILE SYNTHESIS AND REACTIONS OF AMINO SELENOLO[2,3-b]PYRIDINE CARBOXYLATE

2015 ◽  
Vol 12 (1) ◽  
pp. 3910-3918 ◽  
Author(s):  
Dr Remon M Zaki ◽  
Prof Adel M. Kamal El-Dean ◽  
Dr Nermin A Marzouk ◽  
Prof Jehan A Micky ◽  
Mrs Rasha H Ahmed
Keyword(s):  
Biological Activity ◽  
Carbonyl Compounds ◽  
Mass Spectra ◽  
The Other ◽  
Pyridine Derivatives ◽  
Facile Synthesis ◽  
High Biological Activity ◽  
Basic Hydrolysis ◽  
Pyridine Carboxylate ◽  
Hydrolysis Of

 Incorporating selenium metal bonded to the pyridine nucleus was achieved by the reaction of selenium metal with 2-chloropyridine carbonitrile 1 in the presence of sodium borohydride as reducing agent. The resulting non isolated selanyl sodium salt was subjected to react with various α-halogenated carbonyl compounds to afford the selenyl pyridine derivatives 3a-f  which compounds 3a-d underwent Thorpe-Ziegler cyclization to give 1-amino-2-substitutedselenolo[2,3-b]pyridine compounds 4a-d, while the other compounds 3e,f failed to be cyclized. Basic hydrolysis of amino selenolo[2,3-b]pyridine carboxylate 4a followed by decarboxylation furnished the corresponding amino selenolopyridine compound 6 which was used as a versatile precursor for synthesis of other heterocyclic compound 7-16. All the newly synthesized compounds were established by elemental and spectral analysis (IR, 1H NMR) in addition to mass spectra for some of them hoping these compounds afforded high biological activity.

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