ChemInform Abstract: Partial Hydrogenations of Unsaturated Carbonyl Compounds and Unsaturated Hydrocarbons over an Oxidized Amorphous Gold-Zirconium Alloy.

ChemInform ◽  
1990 ◽  
Vol 21 (49) ◽  
Author(s):  
M. SHIBATA ◽  
H. KIMURA ◽  
T. MASUMOTO
Keyword(s):  
Carbonyl Compounds ◽  
Zirconium Alloy ◽  
Unsaturated Hydrocarbons

scholarly journals Nickel-Catalyzed Cycloaddition of Unsaturated Hydrocarbons and Carbonyl Compounds

2005 ◽  
Vol 7 (21) ◽  
pp. 4785-4785 ◽  
Author(s):  
Thomas N. Tekavec ◽  
Janis Louie
Keyword(s):  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons

Highly selective oxidation of unsaturated hydrocarbons to carbonyl compounds by two-phase catalysis

Tetrahedron ◽  
2016 ◽  
Vol 72 (42) ◽  
pp. 6705-6710 ◽  
Author(s):  
Chun Mi ◽  
Lu Li ◽  
Xiang-Guang Meng ◽  
Ren-Qiang Yang ◽  
Xiao-Hong Liao
Keyword(s):  
Selective Oxidation ◽  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons ◽  
Two Phase

Nickel-Catalyzed Cycloaddition of Unsaturated Hydrocarbons and Carbonyl Compounds

2005 ◽  
Vol 7 (18) ◽  
pp. 4037-4039 ◽  
Author(s):  
Thomas N. Tekevac ◽  
Janis Louie
Keyword(s):  
Carbonyl Compounds ◽  
Unsaturated Hydrocarbons

Transition-Metal-Catalyzed Asymmetric Allylation of Carbonyl Compounds with Unsaturated Hydrocarbons

Synthesis ◽  
2017 ◽  
Vol 50 (05) ◽  
pp. 956-967 ◽  
Author(s):  
Liu-Zhu Gong ◽  
Pu-Sheng Wang ◽  
Meng-Lan Shen
Keyword(s):  
Transition Metal ◽  
Carbonyl Compounds ◽  
Building Blocks ◽  
Asymmetric Allylation ◽  
Unsaturated Hydrocarbons ◽  
Homoallylic Alcohols ◽  
Carbon Carbon Bonds ◽  
Transition Metal Catalyzed ◽  
Metal Catalyzed ◽  
Direct Use

The asymmetric allylation of carbonyl compounds is an important process for the formation of carbon–carbon bonds, generating optically active homoallylic alcohols that are versatile building blocks with widespread applications in organic synthesis. The use of readily available unsaturated hydrocarbons as allylating reagents in the transition-metal-catalyzed asymmetric allylation has received increasing interest as either a step- or an atom-economy alternative. This review summarizes transition-metal-catalyzed enantioselective allylations on the basis of the ‘indirect’ and ‘direct’ use of simple unsaturated hydrocarbons (include dienes, allenes, alkynes, and alkenes) as allylating reagents, with emphasis on highlighting conceptually novel reactions.1 Introduction2 ‘Indirect’ Use of Unsaturated Hydrocarbons in Asymmetric Allylation of Carbonyl Compounds2.1 Enantioselective Allylation with 1,3-Dienes2.2 Enantioselective Allylation with Allenes2.3 Enantioselective Allylation with Alkenes3 ‘Direct’ Use of Unsaturated Hydrocarbons in Asymmetric Allylation of Carbonyl Compounds3.1 Enantioselective Allylation with 1,3-Dienes3.2 Enantioselective Allylation with Allenes3.3 Enantioselective Allylation with Alkynes3.4 Enantioselective Allylation with Alkenes4 Conclusions

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