Toward an Enantioselective Total Synthesis of Sarain A:  Construction of an Advanced Intermediate and Rearrangement of the Sarain A Core under Mild Conditions

2005 ◽  
Vol 7 (5) ◽  
pp. 933-936 ◽  
Author(s):  
Christopher J. Douglas ◽  
Sheldon Hiebert ◽  
Larry E. Overman
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis ◽  
Mild Conditions ◽  
Sarain A

Enantioselective total synthesis of furofuran lignans via Pd-catalyzed asymmetric allylic cycloadditon of vinylethylene carbonates with 2-nitroacrylates

2020 ◽  
Vol 56 (82) ◽  
pp. 12431-12434
Author(s):  
Can Zhao ◽  
Ijaz Khan ◽  
Yong Jian Zhang
Keyword(s):  
Total Synthesis ◽  
Efficient Approach ◽  
Enantioselective Total Synthesis ◽  
Mild Conditions

Herein, a practical and efficient approach to tetrahydrofurans with three-stereocenters has been developed through Pd-catalyzed asymmetric allylic cycloaddition of vinylethylene carbonates (VECs) with 2-nitroacrylates under mild conditions.

Organophotoredox-Catalyzed C–H Alkylation of Imidazoheterocycles with Malonates: Total Synthesis of Zolpidem

Synthesis ◽  
2020 ◽  
Author(s):  
Narendra R. Chaubey ◽  
Anant R. Kapdi ◽  
Biswanath Maity
Keyword(s):  
Total Synthesis ◽  
Room Temperature ◽  
Drug Molecule ◽  
Bond Functionalization ◽  
First Report ◽  
Mild Conditions ◽  
The Past ◽  
Hypnotic Drug ◽  
Free Environment

AbstractOrganophotocatalytic C–H bond functionalization has attracted a lot of attention in the past several years due to the possibility of catalyzing reactions in a metal- and peroxide-free environment. Continuing on these lines, an organophotoredox-catalyzed C–H functionalization of imidazo[1,2-a]pyridines and related heterocycles with bromomalonates under mild conditions is reported, providing excellent yields of the products at room temperature. This is the first report involving malonates as coupling partners leading to the synthesis of a range of functionalized products including total synthesis of zolpidem, a sedative­-hypnotic drug molecule.

scholarly journals Enantioselective Total Synthesis of (+)‐Garsubellin A

2021 ◽  
Author(s):  
Dongseok Jang ◽  
Minchul Choi ◽  
Jinglong Chen ◽  
Chulbom Lee
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

Enantioselective Total Synthesis of ( – )‐Spiroxins A, C and D

2021 ◽  
Author(s):  
Xin Shu ◽  
Chong-Chong Chen ◽  
Tao Yu ◽  
Jiayi Yang ◽  
Xiangdong Hu
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

Unified enantioselective total synthesis of 3,6-dioxygenated diketopiperazine natural products, diatretol and lepistamides A, B and C

2021 ◽  
Vol 67 ◽  
pp. 152895
Author(s):  
Shu Takahashi ◽  
Aoi Kimishima ◽  
Tomoyasu Hirose ◽  
Takeshi Yamada ◽  
Akihiro Sugawara ◽  
...  
Keyword(s):  
Natural Products ◽  
Total Synthesis ◽  
Enantioselective Total Synthesis

Enantioselective total synthesis of sesquiterpenoid phellilane L and its diastereomer

Tetrahedron ◽  
2021 ◽  
Vol 87 ◽  
pp. 132110
Author(s):  
Gullapalli Kumaraswamy ◽  
Vankudoth Ramesh ◽  
Swargam Vijaykumar
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis

A concise enantioselective total synthesis of rhizoxin D

2002 ◽  
Vol 43 (3) ◽  
pp. 493-497 ◽  
Author(s):  
Ian S. Mitchell ◽  
Gerald Pattenden ◽  
Jeffrey P. Stonehouse
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis ◽  
Rhizoxin D

ChemInform Abstract: An Enantioselective Total Synthesis of (+)-Cassiol.

ChemInform ◽  
2010 ◽  
Vol 28 (15) ◽  
pp. no-no
Author(s):  
O. IRIE ◽  
Y. FUJIWARA ◽  
H. NEMOTO ◽  
K. SHISHIDO
Keyword(s):  
Total Synthesis ◽  
Enantioselective Total Synthesis
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