Intramolecular Aromatic 1,5-Hydrogen Transfer in Free Radical Reactions III. Reactivity of Diaryl Ketones, Ethers, Thioethers, Sulfoxydes, and Sulfones. An Experimental and Theoretical Study

2003 ◽  
Vol 5 (8) ◽  
pp. 1175-1178 ◽  
Author(s):  
Sandor Karady ◽  
Jordan M. Cummins ◽  
J. J. Dannenberg ◽  
Emma del Rio ◽  
Peter G. Dormer ◽  
...  
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Theoretical Study ◽  
Radical Reactions ◽  
Free Radical Reactions

Free-Radical Reactions under Diffusional Constraints:  Orientation Does Matter in Hydrogen Transfer

2003 ◽  
Vol 125 (39) ◽  
pp. 11806-11807 ◽  
Author(s):  
A. C. Buchanan ◽  
Michelle K. Kidder ◽  
Phillip F. Britt
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Radical Reactions ◽  
Free Radical Reactions

Methyl and Hydrogen Transfer in Free Radical Reactions

2020 ◽  
Vol 34 (2) ◽  
pp. 1698-1709 ◽  
Author(s):  
Joy H. Tannous ◽  
Arno de Klerk
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Radical Reactions ◽  
Free Radical Reactions

ChemInform Abstract: Intramolecular Aromatic 1,5-Hydrogen Transfer in Free Radical Reactions. Part 2. Rearrangement of Iodobenzophenones.

ChemInform ◽  
2010 ◽  
Vol 30 (43) ◽  
pp. no-no
Author(s):  
Jordan M. Cummins ◽  
Ulf-H. Dolling ◽  
Alan W. Douglas ◽  
Sandor Karady ◽  
William R. Leonard Jr. ◽  
...  
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Radical Reactions ◽  
Free Radical Reactions

Intramolecular aromatic 1,5-hydrogen transfer in free radical reactions. II. Rearrangement of iodobenzophenones

1999 ◽  
Vol 40 (34) ◽  
pp. 6153-6156 ◽  
Author(s):  
Jordan M. Cummins ◽  
Ulf-H. Dolling ◽  
Alan W. Douglas ◽  
Sandor Karady ◽  
William R. Leonard ◽  
...  
Keyword(s):  
Free Radical ◽  
Hydrogen Transfer ◽  
Radical Reactions ◽  
Free Radical Reactions

Influence of the solvent on the transmission of polar effects in free radical reactions. A theoretical study

1988 ◽  
Vol 53 (11) ◽  
pp. 2714-2721 ◽  
Author(s):  
Robert Ponec ◽  
Milan Hájek
Keyword(s):  
Free Radical ◽  
Solvent Effects ◽  
Theoretical Study ◽  
Chemical Reactivity ◽  
Theoretical Description ◽  
Radical Reactions ◽  
Combined Approach ◽  
Free Radical Reactions ◽  
General Methodology ◽  
Charge Model

The influence of the solvents on the transmission of polar effects in free radical reactions has been analysed theoretically by using the combined approach based on the incorporation of delocalizabilities as static indices of chemical reactivity into the framework of virtual charge model. The possibility of using this theoretical description as a general methodology of characterizing solvent effects is discussed.

The initial reaction mechanism and thermal sensitivity of a fluoropolymer-containing energetic molecular system: the coupling effect of interfacial interactions and free radical reactions

CrystEngComm ◽  
2021 ◽  
Vol 23 (16) ◽  
pp. 3006-3014
Author(s):  
Wen Qian
Keyword(s):  
Free Radical ◽  
Coupling Effect ◽  
Molecular System ◽  
Thermal Sensitivity ◽  
Radical Reactions ◽  
Initial Reaction ◽  
Interfacial Interactions ◽  
Free Radical Reactions ◽  
Molecular Systems ◽  
Reactive Molecular Dynamics

A strategy combining classic and reactive molecular dynamics is applied to find the coupling effect of interfacial interactions and free radical reactions during the initial thermal decomposition of fluoropolymer-containing molecular systems.

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