Hydrophobic Interactions of Poly(N-isopropylacrylamide) with Hydrophobically Modified Poly(sodium acrylate) in Aqueous Solution

1997 ◽  
Vol 30 (26) ◽  
pp. 8293-8297 ◽  
Author(s):  
G. Bokias ◽  
D. Hourdet ◽  
I. Iliopoulos ◽  
G. Staikos ◽  
R. Audebert
Keyword(s):  
Aqueous Solution ◽  
Hydrophobic Interactions ◽  
Sodium Acrylate ◽  
Hydrophobically Modified

Novel pH-Sensitive Poly(Vinyl Alcohol) Based Polyampholyte as Pervaporation Membrane

2016 ◽  
Vol 852 ◽  
pp. 979-983
Author(s):  
Ping Rui Meng ◽  
Liang Bo Li
Keyword(s):  
Aqueous Solution ◽  
Vinyl Alcohol ◽  
Water Resistance ◽  
Graft Copolymerization ◽  
Sodium Acrylate ◽  
Poly Vinyl Alcohol ◽  
Permeate Flux ◽  
Ft Ir ◽  
Ethanol Aqueous Solution ◽  
Poly Acrylamide

Sodium acrylate (NaAA) and acrylamide (AM) were grafted onto poly (vinyl alcohol) (PVA) using potassium persulfate as an initiator, Graft copolymerization namely poly (vinyl alcohol)-g-poly (acrylamide/sodium acrylate) (PVA-g-PAM/SAC). The poly (vinyl alcohol)-g-poly (vinylamine/sodium acrylate) (PVAMC) was prepraed by Hofmann rearrangement.The PVAMC homogeneous membrane was characterized by fourier transform infrared spectroscopy (FT-IR), scanning electron microscopy (SEM).The water resistance of the PVAMC membranes is the best when pH of the PVAMC solutions was 4, at that time the numbers of-NH3+ and-COO- groups trended to be equal, so the isoelectric point was pH=4. At 90 °C the pervaporation of PVAMC composite membrane was tested and showed that the separation factor and the permeate flux were about 1001 and 1341 g/(m2·h) for 90wt% ethanol aqueous solution, and they were about 1297 and 1040 g/(m2·h) for 90wt% isopropanol aqueous solution.

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