Effect of Relative Humidity on the Young’s Modulus of Polyelectrolyte Multilayer Films and Related Nonionic Polymers

2008 ◽  
Vol 41 (15) ◽  
pp. 5793-5798 ◽  
Author(s):  
Adam J. Nolte ◽  
Neil D. Treat ◽  
Robert E. Cohen ◽  
Michael F. Rubner
TAPPI Journal ◽  
2013 ◽  
Vol 12 (4) ◽  
pp. 9-17 ◽  
Author(s):  
KEVIN H. M. KAN ◽  
EMILY D. CRANSTON

The Young’s modulus of multilayer films containing cellulose nanocrystals (CNCs) and polyethyleneimine (PEI) was measured using a buckling-based method and compared to analogous films containing nanofibrillated cellulose (NFC) and PEI [1]. For films 61 nm to 1.7 μm thick, the Young’s modulus was constant but strongly dependent on relative humidity. Films were stiffer at lower relative humidities, with modulus values of 16 ± 5, 12 ± 1, and 3.5 ± 0.3 GPa at 30%, 42%, and 64% relative humidities, respectively. CNC/PEI films had larger elastic moduli than NFC/PEI films. Both types of nanocellulose multilayer films showed the same modulus dependence on relative humidity over the range studied. Results suggest that ambient water might have an even more pronounced role in nanocomposites than in traditional natural fiber-reinforced composites. This straightforward buckling-based method has quantified mechanical properties and provided a useful comparison between CNC and NFC films. Furthermore, it qualitatively assesses that the components in the composite film are highly compatible and that the hydrophilicity and hygroscopicity of cellulose and PEI combined do not allow for the full mechanical potential of crystalline cellulose nanoelements to be exploited. This work is one approach toward finding dependable methods to characterize nanocellulose, specifically cellulosic thin films, which is increasingly important as we extract nanocellulose from wood, plants, algae, bacteria, and animals and enter a new age of cellulose materials.


Micromachines ◽  
2017 ◽  
Vol 8 (7) ◽  
pp. 201 ◽  
Author(s):  
Xin-Ge Guo ◽  
Zai-Fa Zhou ◽  
Chao Sun ◽  
Wei-Hua Li ◽  
Qing-An Huang

1993 ◽  
Vol 12 (16) ◽  
pp. 1333-1334 ◽  
Author(s):  
K. Nallamshetty ◽  
M. A. Angadi ◽  
R. Whiting

2013 ◽  
Vol 748 ◽  
pp. 241-246
Author(s):  
Mohd Hilmi Othman ◽  
Hasan Sulaiman ◽  
N.M. Main ◽  
L. Li

This research was conducted to evaluate the strength and folding performance of polypropylene packaging samples, when exposed to hot air and high humidity condition. Three types of polypropylene samples were chosen, which were flat plastic, plastic with hinges, and plastic film. All of these samples were tested for tensile strength; except plastic with hinges that received additional test to evaluate the folding endurance. American Society for Testing and Materials (ASTM) D638 standard was applied to analyze the mechanical strength of these plastics. This standard was used to determine the value of stress, strain, and Young’s modulus. Each sample was exposed to different temperature settings, which were 20°C, 25°C, and 30°C for high humidity condition and 60°C, 65°C, and 70°C for hot air condition. As for the folding endurance test, the hot air temperatures were selected at 60°C, 65°C and 70°C and for the high humidity condition, the range of relative humidity were set at 50%, 55% and 60%. Based on the tensile test results, the values of stress and Young’s modulus were higher at higher humidity as compared with the values under hot air condition. However the strain value was the opposite of the stress and Young’s modulus, whereby the values started to deceive under high humidity condition, but kept on increasing under hot air condition. In folding endurance test, it was confirmed that the hinge performed better under hot air environment than high humidity. As the relative humidity increases, the average number of folding decreased from 3.00x106 to 2.89x106 cycles. In the other hand, thevalue of folding numbers increased from 3.34x106 to 3.37x106, with increasing temperature. In conclusion, through this performance analysis, the outcomes can be applied to other packaging materials and appliances, which are related to high temperature and high humidity condition.


2019 ◽  
Vol 107 (2) ◽  
pp. 207 ◽  
Author(s):  
Jaroslav Čech ◽  
Petr Haušild ◽  
Miroslav Karlík ◽  
Veronika Kadlecová ◽  
Jiří Čapek ◽  
...  

FeAl20Si20 (wt.%) powders prepared by mechanical alloying from different initial feedstock materials (Fe, Al, Si, FeAl27) were investigated in this study. Scanning electron microscopy, X-ray diffraction and nanoindentation techniques were used to analyze microstructure, phase composition and mechanical properties (hardness and Young’s modulus). Finite element model was developed to account for the decrease in measured values of mechanical properties of powder particles with increasing penetration depth caused by surrounding soft resin used for embedding powder particles. Progressive homogenization of the powders’ microstructure and an increase of hardness and Young’s modulus with milling time were observed and the time for complete homogenization was estimated.


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