Metallocene-Mediated Asymmetric Coordination Polymerization of Polar Vinyl Monomers to Optically Active, Stereoregular Polymers

2008 ◽  
Vol 41 (10) ◽  
pp. 3405-3416 ◽  
Author(s):  
Garret M. Miyake ◽  
Eugene Y.-X. Chen
Keyword(s):  
Optically Active ◽  
Vinyl Monomers ◽  
Coordination Polymerization ◽  
Stereoregular Polymers ◽  
Asymmetric Coordination

Catalyst-Site-Controlled Coordination Polymerization of Polar Vinyl Monomers to Highly Syndiotactic Polymers

2010 ◽  
Vol 132 (8) ◽  
pp. 2695-2709 ◽  
Author(s):  
Yuetao Zhang ◽  
Yalan Ning ◽  
Lucia Caporaso ◽  
Luigi Cavallo ◽  
Eugene Y.-X. Chen
Keyword(s):  
Vinyl Monomers ◽  
Coordination Polymerization

Neodymium Catalysts for Polymerization of Dienes, Vinyl Monomers, and ε-Caprolactone

2021 ◽  
Author(s):  
Mihaela C. Stefan ◽  
Erika Calubaquib ◽  
Hanghang Wang ◽  
John Michael Orolaza Cue ◽  
Justin T Miller ◽  
...  
Keyword(s):  
Rare Earth ◽  
Complex Structure ◽  
Vinyl Monomers ◽  
Coordination Polymerization ◽  
The Rare Earth

Among the rare-earth catalysts, neodymium-based catalysts are systematically investigated due to their efficiency and versatility. Still, the correlation between the complex structure and the catalytic coordination polymerization is not yet...

“Arm-first” approach for the synthesis of star-shaped stereoregular polymers through living coordination polymerization

2017 ◽  
Vol 8 (9) ◽  
pp. 1449-1453 ◽  
Author(s):  
Zhenghai Shi ◽  
Fang Guo ◽  
Rui Tan ◽  
Hui Niu ◽  
Tingting Li ◽  
...  
Keyword(s):  
Star Polymers ◽  
Catalyst System ◽  
Coordination Polymerization ◽  
Polymerization Mechanism ◽  
System P ◽  
Stereoregular Polymers ◽  
First Time ◽  
Half Sandwich

Stereoregular star polymers were synthesized through an “arm-first” approach via a living coordination polymerization mechanism for the first time using a half-sandwich scandium catalyst system.

scholarly journals Stereoregular Polymers. IX. Polymerization of Optically Active α-Olefins

1961 ◽  
Vol 34 (11) ◽  
pp. 1673-1678 ◽  
Author(s):  
Shun’ichi Nozakura ◽  
Shigeru Takeuchi ◽  
Heimei Yuki ◽  
Shunsuke Murahashi
Keyword(s):  
Optically Active ◽  
Stereoregular Polymers
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