Catalyst-Site-Controlled Coordination Polymerization of Polar Vinyl Monomers to Highly Syndiotactic Polymers

2010 ◽  
Vol 132 (8) ◽  
pp. 2695-2709 ◽  
Author(s):  
Yuetao Zhang ◽  
Yalan Ning ◽  
Lucia Caporaso ◽  
Luigi Cavallo ◽  
Eugene Y.-X. Chen
Keyword(s):  
Vinyl Monomers ◽  
Coordination Polymerization

Neodymium Catalysts for Polymerization of Dienes, Vinyl Monomers, and ε-Caprolactone

2021 ◽  
Author(s):  
Mihaela C. Stefan ◽  
Erika Calubaquib ◽  
Hanghang Wang ◽  
John Michael Orolaza Cue ◽  
Justin T Miller ◽  
...  
Keyword(s):  
Rare Earth ◽  
Complex Structure ◽  
Vinyl Monomers ◽  
Coordination Polymerization ◽  
The Rare Earth

Among the rare-earth catalysts, neodymium-based catalysts are systematically investigated due to their efficiency and versatility. Still, the correlation between the complex structure and the catalytic coordination polymerization is not yet...

Coordination polymerization of renewable butyrolactone-based vinyl monomers by lanthanide and early metal catalysts

2010 ◽  
Vol 39 (29) ◽  
pp. 6710 ◽  
Author(s):  
Garret M. Miyake ◽  
Stacie E. Newton ◽  
Wesley R. Mariott ◽  
Eugene Y.-X. Chen
Keyword(s):  
Metal Catalysts ◽  
Vinyl Monomers ◽  
Coordination Polymerization

Palladium Promoted Copolymerization of Carbon Monoxide with Polar or Nonpolar Olefinic Monomers

2020 ◽  
Vol 24 ◽  
Author(s):  
Yanlin Zong ◽  
Qiankun Li ◽  
Hongliang Mu ◽  
Zhongbao Jian
Keyword(s):  
Carbon Monoxide ◽  
Physical Properties ◽  
Vinyl Monomers ◽  
Pd Catalysts ◽  
Catalytic Systems

Abstract:: The copolymers of carbon monoxide (CO) and olefins, namely polyketones, are a family of widely used materi-als. In the catalytic preparation of these materials, palladium(II) catalysts represent the most successful catalytic systems. The production of both alternating and non-alternating polyketones has been achieved, with great difference in their physical properties. Herein, a variety of palladium(II) catalysts employed for the copolymerization of CO with various olefinic mon-omers such as ethylene, α-olefins, styrene and polar vinyl monomers are fully summarized. The influence of important fac-tors such as solvents and counterions on specific copolymerization, is also discussed. This review aims to enlighten the de-sign of new Pd catalysts with improved properties, as well as the development of new polyketone materials.

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