Phenols and Carbon Compounds as Efficient Organic Catalysts for Reversible Chain Transfer Catalyzed Living Radical Polymerization (RTCP)

2010 ◽  
Vol 43 (19) ◽  
pp. 7971-7978 ◽  
Author(s):  
Atsushi Goto ◽  
Norihiro Hirai ◽  
Koji Nagasawa ◽  
Yoshinobu Tsujii ◽  
Takeshi Fukuda ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Living Radical Polymerization ◽  
Carbon Compounds ◽  
Reversible Chain Transfer ◽  
Organic Catalysts

Living Radical Polymerization with Nitrogen Catalyst: Reversible Chain Transfer Catalyzed Polymerization withN-Iodosuccinimide

2008 ◽  
Vol 41 (17) ◽  
pp. 6261-6264 ◽  
Author(s):  
Atsushi Goto ◽  
Norihiro Hirai ◽  
Tsutomu Wakada ◽  
Koji Nagasawa ◽  
Yoshinobu Tsujii ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Living Radical Polymerization ◽  
Reversible Chain Transfer ◽  
Catalyzed Polymerization

Living Radical Polymerization with Reversible Addition−Fragmentation Chain Transfer (RAFT Polymerization) Using Dithiocarbamates as Chain Transfer Agents

1999 ◽  
Vol 32 (21) ◽  
pp. 6977-6980 ◽  
Author(s):  
Roshan T. A. Mayadunne ◽  
Ezio Rizzardo ◽  
John Chiefari ◽  
Yen Kwong Chong ◽  
Graeme Moad ◽  
...  
Keyword(s):  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Reversible Addition ◽  
Transfer Agents

Controlled/Living Radical Polymerization of Semifluorinated (Meth)acrylates

Synlett ◽  
2018 ◽  
Vol 29 (12) ◽  
pp. 1543-1551 ◽  
Author(s):  
Mao Chen ◽  
Honghong Gong ◽  
Yu Gu
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Chain Transfer ◽  
Raft Polymerization ◽  
Living Radical Polymerization ◽  
Atom Transfer ◽  
Reversible Addition ◽  
Controlled Living Radical Polymerization ◽  
Chain Transfer Polymerization ◽  
Semifluorinated Polymers

Fluorinated polymers are important materials for applications in many areas. This article summarizes the development of controlled/living radical polymerization (CRP) of semifluorinated (meth)acrylates, and briefly introduces their reaction mechanisms. While the classical CRP such as atom transfer radical polymerization (ATRP), reversible addition-fragmentation chain transfer (RAFT) polymerization and nitroxide-mediated radical polymerization (NMP) have promoted the preparation of semifluorinated polymers with tailor-designed architectures, recent development of photo-CRP has led to unprecedented accuracy and monomer scope. We expect that synthetic advances will facilitate the engineering of advanced fluorinated materials with unique properties.1 Introduction2 Atom Transfer Radical Polymerization3 Reversible Addition-Fragmentation Chain Transfer Polymerization4 Nitroxide-Mediated Radical Polymerization5 Photo-CRP Mediated with Metal Complexes6 Metal-free Photo-CRP7 Conclusion

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