Rational Selection of Initiating/Catalytic Systems for the Copper-Mediated Atom Transfer Radical Polymerization of Basic Monomers in Protic Media:  ATRP of 4-Vinylpyridine

2006 ◽  
Vol 39 (20) ◽  
pp. 6817-6824 ◽  
Author(s):  
Nicolay V. Tsarevsky ◽  
Wade A. Braunecker ◽  
Samuel J. Brooks ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Rational Selection ◽  
Catalytic Systems ◽  
Selection Of ◽  
Protic Media

New supported-catalytic systems for atom transfer radical polymerization

Polymer ◽  
2015 ◽  
Vol 77 ◽  
pp. 199-207 ◽  
Author(s):  
Claire Bernhardt ◽  
Chirine Ben Osman ◽  
Bernadette Charleux ◽  
François Stoffelbach
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Catalytic Systems

Well-Defined Biocompatible Block Copolymers via Atom Transfer Radical Polymerization of 2-Methacryloyloxyethyl Phosphorylcholine in Protic Media

2003 ◽  
Vol 36 (10) ◽  
pp. 3475-3484 ◽  
Author(s):  
Yinghua Ma ◽  
Yiqing Tang ◽  
Norman C. Billingham ◽  
Steven P. Armes ◽  
Andrew L. Lewis ◽  
...  
Keyword(s):  
Block Copolymers ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Protic Media

Water-Dispersible Carbon Black Nanocomposites Prepared by Surface-Initiated Atom Transfer Radical Polymerization in Protic Media

2006 ◽  
Vol 39 (2) ◽  
pp. 548-556 ◽  
Author(s):  
Tianqi Liu ◽  
Shijun Jia ◽  
Tomasz Kowalewski ◽  
Krzysztof Matyjaszewski ◽  
Rosa Casado-Portilla ◽  
...  
Keyword(s):  
Carbon Black ◽  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Water Dispersible ◽  
Protic Media

scholarly journals Iron Catalysts in Atom Transfer Radical Polymerization

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1648 ◽  
Author(s):  
Sajjad Dadashi-Silab ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
High Efficiency ◽  
Catalyst Design ◽  
Iron Catalysts ◽  
Atom Transfer ◽  
Controlled Polymerization ◽  
Catalytic Systems ◽  
Functional Monomers ◽  
Styrene Atrp

Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of functional monomers. In addition to copper, iron-based complexes offer new opportunities in ATRP catalysis to develop environmentally friendly, less toxic, inexpensive, and abundant catalytic systems. Despite the high efficiency of iron catalysts in controlling polymerization of various monomers including methacrylates and styrene, ATRP of acrylate-based monomers by iron catalysts still remains a challenge. In this paper, we review the fundamentals and recent advances of iron-catalyzed ATRP focusing on development of ligands, catalyst design, and techniques used for iron catalysis in ATRP.

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