Elaboration of well-defined Rasta resins and their use as supported catalytic systems for atom transfer radical polymerization

2006 ◽  
Vol 44 (18) ◽  
pp. 5316-5328 ◽  
Author(s):  
David Fournier ◽  
Sagrario Pascual ◽  
Véronique Montembault ◽  
Laurent Fontaine
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Catalytic Systems

New supported-catalytic systems for atom transfer radical polymerization

Polymer ◽  
2015 ◽  
Vol 77 ◽  
pp. 199-207 ◽  
Author(s):  
Claire Bernhardt ◽  
Chirine Ben Osman ◽  
Bernadette Charleux ◽  
François Stoffelbach
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Atom Transfer ◽  
Catalytic Systems

scholarly journals Iron Catalysts in Atom Transfer Radical Polymerization

Molecules ◽  
2020 ◽  
Vol 25 (7) ◽  
pp. 1648 ◽  
Author(s):  
Sajjad Dadashi-Silab ◽  
Krzysztof Matyjaszewski
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
High Efficiency ◽  
Catalyst Design ◽  
Iron Catalysts ◽  
Atom Transfer ◽  
Controlled Polymerization ◽  
Catalytic Systems ◽  
Functional Monomers ◽  
Styrene Atrp

Catalysts are essential for mediating a controlled polymerization in atom transfer radical polymerization (ATRP). Copper-based catalysts are widely explored in ATRP and are highly efficient, leading to well-controlled polymerization of a variety of functional monomers. In addition to copper, iron-based complexes offer new opportunities in ATRP catalysis to develop environmentally friendly, less toxic, inexpensive, and abundant catalytic systems. Despite the high efficiency of iron catalysts in controlling polymerization of various monomers including methacrylates and styrene, ATRP of acrylate-based monomers by iron catalysts still remains a challenge. In this paper, we review the fundamentals and recent advances of iron-catalyzed ATRP focusing on development of ligands, catalyst design, and techniques used for iron catalysis in ATRP.

Redox Responsive Behavior of Thiol/Disulfide-Functionalized Star Polymers Synthesized via Atom Transfer Radical Polymerization

2010 ◽  
Vol 43 (9) ◽  
pp. 4133-4139 ◽  
Author(s):  
Jun Kamada ◽  
Kaloian Koynov ◽  
Cathrin Corten ◽  
Azhar Juhari ◽  
Jeong Ae Yoon ◽  
...  
Keyword(s):  
Atom Transfer Radical Polymerization ◽  
Radical Polymerization ◽  
Star Polymers ◽  
Atom Transfer ◽  
Redox Responsive ◽  
Responsive Behavior
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