Phase Behavior of Mixtures of Block Copolymer and Homopolymers in Thin Films and Bulk

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For P(S-b-MMA)/PS mixtures with ϕPS = 64%, PL exists in thin films annealed at 230–270 °C. For thick films, thermal annealing at 245–270 °C produces both PL and DG of various fractions. PL becomes the only discernible phase in thick films annealed at 230 °C.


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