Properties of low molecular weight block copolymers. 3. Mixtures of styrene-dimethylsiloxane diblock copolymers with polystyrene

1982 ◽  
Vol 15 (2) ◽  
pp. 367-370 ◽  
Author(s):  
Zhong He Lu ◽  
Sonja Krause ◽  
Magdy Iskandar
1993 ◽  
Vol 58 (11) ◽  
pp. 2574-2582 ◽  
Author(s):  
Jaroslav Stehlíček ◽  
Rudolf Puffr

Poly(2,6-dimethyl-1,4-phenylene oxide)-poly(6-hexanelactam) diblock copolymers were prepared from low-molecular weight poly(2,6-dimethyl-1,4-phenylene oxide) by transforming its phenolic end groups via the reaction with 2,4-tolylene diisocyanate and 6-hexanelactam to polymeric initiators and the subsequent anionic polymerization of 6-hexanelactam. The polymerization of 6-hexanelactam was carried out in bulk or toluene solution. The content of the 6-hexanelactam homopolymer was estimated by TLC showing that the pure diblock copolymer can be prepared in toluene. The reason for relatively low yields is discussed.


Polymers ◽  
2011 ◽  
Vol 3 (2) ◽  
pp. 693-718 ◽  
Author(s):  
Olga Samsonova ◽  
Christian Pfeiffer ◽  
Markus Hellmund ◽  
Olivia M. Merkel ◽  
Thomas Kissel

Sign in / Sign up

Export Citation Format

Share Document