Chain-Length-Dependent Termination Rate Processes in Free-Radical Polymerizations. 3. Styrene Polymerizations with and without Added Inert Diluent as an Experimental Test of Model

1995 ◽  
Vol 28 (10) ◽  
pp. 3637-3649 ◽  
Author(s):  
Peter A. G. M. Scheren ◽  
Gregory T. Russell ◽  
David F. Sangster ◽  
Robert G. Gilbert ◽  
Anton L. German
Keyword(s):  
Free Radical ◽  
Chain Length ◽  
Experimental Test ◽  
Inert Diluent ◽  
Termination Rate ◽  
Rate Processes ◽  
Radical Polymerizations

Chain-length-dependent termination rate processes in free-radical polymerizations. 1. Theory

1992 ◽  
Vol 25 (9) ◽  
pp. 2459-2469 ◽  
Author(s):  
Gregory T. Russell ◽  
Robert G. Gilbert ◽  
Donald H. Napper
Keyword(s):  
Free Radical ◽  
Chain Length ◽  
Termination Rate ◽  
Rate Processes ◽  
Radical Polymerizations

When Mayo falls short (Ctr ≫ 1): the use of cumulative chain length distribution data in the determination of chain transfer constants (Ctr) for radical polymerizations

2020 ◽  
Vol 11 (26) ◽  
pp. 4281-4289
Author(s):  
Matt K. Donald ◽  
Stefan A. F. Bon
Keyword(s):  
Molecular Weight ◽  
Free Radical ◽  
Chain Length ◽  
Weight Distribution ◽  
Chain Transfer ◽  
Length Distribution ◽  
Distribution Data ◽  
Chain Length Distribution ◽  
Radical Polymerizations

A method to determine chain transfer constants in free radical polymerizations that are >1 using molecular weight distribution data.

Mapping Chain Length and Conversion Dependent Termination Rate Coefficients in Methyl Acrylate Free Radical Polymerization

2005 ◽  
Vol 38 (24) ◽  
pp. 10323-10327 ◽  
Author(s):  
Alexander Theis ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Methyl Acrylate ◽  
Free Radical Polymerization ◽  
Rate Coefficients ◽  
Termination Rate
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