A Theoretical Description of a Method for Model-Independent Determination of Bimolecular Chain-Length-Dependent Free-Radical-Termination Rate Coefficients

1997 ◽  
Vol 30 (22) ◽  
pp. 6743-6753 ◽  
Author(s):  
John B. L. de Kock ◽  
Bert Klumperman ◽  
Alex M. van Herk ◽  
Anton L. German
Keyword(s):  
Free Radical ◽  
Chain Length ◽  
Theoretical Description ◽  
Rate Coefficients ◽  
Termination Rate ◽  
Independent Determination ◽  
Model Independent

Mapping Chain Length and Conversion Dependent Termination Rate Coefficients in Methyl Acrylate Free Radical Polymerization

2005 ◽  
Vol 38 (24) ◽  
pp. 10323-10327 ◽  
Author(s):  
Alexander Theis ◽  
Thomas P. Davis ◽  
Martina H. Stenzel ◽  
Christopher Barner-Kowollik
Keyword(s):  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Methyl Acrylate ◽  
Free Radical Polymerization ◽  
Rate Coefficients ◽  
Termination Rate

scholarly journals Model-Independent Determination of the Spin of the Ω− and Its Polarization Alignment in ψ(3686)→Ω−Ω¯+

2021 ◽  
Vol 126 (9) ◽  
Author(s):  
M. Ablikim ◽  
M. N. Achasov ◽  
P. Adlarson ◽  
S. Ahmed ◽  
M. Albrecht ◽  
...  
Keyword(s):  
Independent Determination ◽  
Model Independent

Model independent determination of GEn from the reaction

1988 ◽  
Vol 206 (2) ◽  
pp. 187-189 ◽  
Author(s):  
E.L. Tomusiak ◽  
H. Arenhövel
Keyword(s):  
Independent Determination ◽  
Model Independent

The Kinetics of Free-Radical Polymerization: Fundamental Aspects

2002 ◽  
Vol 55 (7) ◽  
pp. 399 ◽  
Author(s):  
G. T. Russell
Keyword(s):  
Molecular Weight ◽  
Steady State ◽  
Free Radical ◽  
Radical Polymerization ◽  
Chain Length ◽  
Free Radical Polymerization ◽  
Length Dependence ◽  
Model Independent ◽  
Living Free Radical Polymerization ◽  
Kinetics Of

Some fundamental aspects of the kinetics of free-radical polymerization are reviewed. So-called classical results for rate and molecular-weight distribution are first of all presented. It is shown how this approach can be built upon when chain-length-dependent termination is allowed, which it always should be. Various termination models are considered, and it is illustrated that although the models are different, rather remarkably they give common, model-independent behaviour. Some leading experimental results regarding the chain-length dependence of termination are summarized, before the chain-length dependence of other reactivities, the variation of reactivities with conversion, and non-steady state experiments are briefly discussed. Finally, living free-radical polymerization as effected by a reversible termination agent is considered. An outline of the kinetics of these systems is given, with the oft-neglected importance of conventional termination being stressed.

Model-independent determination of the degree of charge transfer in molecular and metal complexes

2015 ◽  
Vol 51 (81) ◽  
pp. 15071-15074 ◽  
Author(s):  
Bora Joo ◽  
Eung-Gun Kim
Keyword(s):  
Charge Transfer ◽  
Metal Complexes ◽  
Active Space ◽  
Model Free ◽  
Independent Determination ◽  
Charge Analysis ◽  
Model Independent ◽  
Degree Of Charge Transfer

Choosing a small active space of electrons for charge analysis allows the model-free determination of the degree of charge transfer.

scholarly journals Improved model-independent determination of the strong-phase difference between D0 and D¯0→KS,L0K+K− decays

2020 ◽  
Vol 102 (5) ◽  
Author(s):  
M. Ablikim ◽  
M. N. Achasov ◽  
P. Adlarson ◽  
S. Ahmed ◽  
M. Albrecht ◽  
...  
Keyword(s):  
Phase Difference ◽  
Strong Phase ◽  
Independent Determination ◽  
Model Independent ◽  
Improved Model
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