Introduction of [2]Catenanes into Langmuir Films and Langmuir−Blodgett Multilayers. A Possible Strategy for Molecular Information Storage Materials

Langmuir ◽  
2000 ◽  
Vol 16 (4) ◽  
pp. 1924-1930 ◽  
Author(s):  
Christopher L. Brown ◽  
Ulrich Jonas ◽  
Jon A. Preece ◽  
Helmut Ringsdorf ◽  
Markus Seitz ◽  
...  
2021 ◽  
Author(s):  
Yan-Lei Lu ◽  
Wen-Long Lan ◽  
Wei Shi ◽  
Qionghua Jin ◽  
Peng Cheng

Photo-induced variation of magnetism from ligand-based electron transfer have been extensively studied because of their potential applications in magneto-optical memory devices, light-responsive switches, and high-density information storage materials. In this...


2002 ◽  
Vol 130 (3) ◽  
pp. 221-227 ◽  
Author(s):  
Krzysztof Noworyta ◽  
Wlodzimierz Kutner ◽  
Gollapalli R Deviprasad ◽  
Francis D’Souza

2021 ◽  
Author(s):  
Guangwei Zhang ◽  
Jihong Zheng ◽  
Zhaoxia Han ◽  
Chunxian Tao

Author(s):  
COLIN L. HONEYBOURNE ◽  
KEVIN J. BARRELL

The synthesis of three novel porphyrins (that are models for mesoporphyrin) requires the synthesis of eight new pyrroles, one new alkyl-3-oxohexanoate and two new dipyrromethanes. The new porphyrin free bases have hydrophobic substitution patterns different from that in mesoporphyrin. We are seeking amphilic porphyrins that will form Langmuir–Blodgett (LB) multilayers without recourse to either long-chain alkyl substituents or fatty acid additives. In this way the influence of the conjugated tetrapyrrole unit on the properties of the multilayer films can be maximized. We report multilayer deposition for porphyrins having the following substituents: CH 3, C 2 H 5, n- C 3 H 7, ( CH 2)2 COOMe ; no additives such as stearic acid, cadmium stearate or mesitylene are required, Y-type deposition being exhibited by the simply substituted pure methyl esters. The variations in proton NMR chemical shift with concentration are reported and the action spectrum of an LB film of a porphyrinato- Zn (II) complex is described. Our observations and conclusions are in sharp (and optimistic) contrast with those of H. Chou et al. (J. Phys. Chem. 98, 383 (1994)), who found that in the absence of steric constraints from bulky aliphatic chains the Langmuir films are so rigid that either no multilayers or multilayers of poor quality are given. We obtain good-quality multilayers (60 layers) for porphyrins bearing eight small substituents.


1991 ◽  
Vol 43 (1-2) ◽  
pp. 2853-2858 ◽  
Author(s):  
A Grupp ◽  
W Zweygart ◽  
M Mehring

2004 ◽  
Vol 52 (10) ◽  
pp. 2847-2862 ◽  
Author(s):  
D.J. Larson ◽  
A.K. Petford-Long ◽  
Y.Q Ma ◽  
A. Cerezo

Sign in / Sign up

Export Citation Format

Share Document