Influence of van der Waals Forces from Metallic Substrates on Fluids Supported on Self-Assembled Monolayers Formed from Alkanethiols

Langmuir ◽  
1997 ◽  
Vol 13 (26) ◽  
pp. 7106-7114 ◽  
Author(s):  
William J. Miller ◽  
Nicholas L. Abbott
Keyword(s):  
Van Der Waals ◽  
Van Der Waals Forces ◽  
Self Assembled Monolayers ◽  
Metallic Substrates ◽  
Assembled Monolayers ◽  
Self Assembled

scholarly journals A van der Waals density functional investigation of carboranethiol self-assembled monolayers on Au(111)

2016 ◽  
Vol 18 (18) ◽  
pp. 12920-12927 ◽  
Author(s):  
Ersen Mete ◽  
Ayşen Yılmaz ◽  
Mehmet Fatih Danışman
Keyword(s):  
Density Functional Theory ◽  
Density Functional ◽  
Van Der Waals ◽  
Density Functional Theory Calculations ◽  
Self Assembled Monolayers ◽  
Functional Theory ◽  
Monolayer Adsorption ◽  
Assembled Monolayers ◽  
Self Assembled ◽  
Functional Investigation

Isolated and full monolayer adsorption of various carboranethiol (C2B10H12S) isomers on the gold(111) surface has been investigated using both the standard and van der Waals density functional theory calculations.

Hydrogen-Bonding versus van der Waals Interactions in Self-Assembled Monolayers of Substituted Isophthalic Acids

Langmuir ◽  
2010 ◽  
Vol 26 (23) ◽  
pp. 18155-18161 ◽  
Author(s):  
Pearl N. Dickerson ◽  
Amber M. Hibberd ◽  
Nuri Oncel ◽  
Steven L. Bernasek
Keyword(s):  
Hydrogen Bonding ◽  
Van Der Waals ◽  
Van Der Waals Interactions ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Mechanical response of nanometer thick self-assembled monolayers on metallic substrates using classical nanoindentation

2011 ◽  
Vol 110 (11) ◽  
pp. 114301 ◽  
Author(s):  
Leila Costelle ◽  
Pasi Jalkanen ◽  
Minna T. Räisänen ◽  
Liina Lind ◽  
Roman Nowak ◽  
...  
Keyword(s):  
Mechanical Response ◽  
Self Assembled Monolayers ◽  
Metallic Substrates ◽  
Assembled Monolayers ◽  
Self Assembled

Electrochemical behavior of self-assembled monolayers based on functionalized oligothiophenes

1998 ◽  
Vol 95 (6) ◽  
pp. 1339-1342 ◽  
Author(s):  
R. Michalitsch ◽  
A. El Kassmi ◽  
P. Lang ◽  
A. Yassar ◽  
F. Garnier
Keyword(s):  
Electrochemical Behavior ◽  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Self Assembled

Imaging of patterned self-assembled monolayers by scanning photoelectron microscopy

2003 ◽  
Vol 104 ◽  
pp. 459-462 ◽  
Author(s):  
R. Klauser ◽  
M. Zharnikov ◽  
I.-H. Hong ◽  
S.-C. Wang ◽  
A. Gölzhäuser ◽  
...  
Keyword(s):  
Self Assembled Monolayers ◽  
Assembled Monolayers ◽  
Scanning Photoelectron Microscopy ◽  
Self Assembled

Self-Assembly of a Chiral Cubic Three-Connected Net from the High Symmetry Molecules C60 and SnI4

2020 ◽  
Author(s):  
Daniel B. Straus ◽  
Robert J. Cava
Keyword(s):  
Organic Synthesis ◽  
Self Assembly ◽  
Van Der Waals ◽  
Van Der Waals Forces ◽  
High Symmetry ◽  
Molecular Chirality ◽  
Chiral Materials ◽  
Self Assembled ◽  
Chiral Centers

The design of new chiral materials usually requires stereoselective organic synthesis to create molecules with chiral centers. Less commonly, achiral molecules can self-assemble into chiral materials, despite the absence of intrinsic molecular chirality. Here, we demonstrate the assembly of high-symmetry molecules into a chiral van der Waals structure by synthesizing crystals of C<sub>60</sub>(SnI<sub>4</sub>)<sub>2</sub> from icosahedral buckminsterfullerene (C<sub>60</sub>) and tetrahedral SnI4 molecules through spontaneous self-assembly. The SnI<sub>4</sub> tetrahedra template the Sn atoms into a chiral cubic three-connected net of the SrSi<sub>2</sub> type that is held together by van der Waals forces. Our results represent the remarkable emergence of a self-assembled chiral material from two of the most highly symmetric molecules, demonstrating that almost any molecular, nanocrystalline, or engineered precursor can be considered when designing chiral assemblies.

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