Nitromethane and Methyl Nitrite Adsorption on Au(111) Surfaces

Langmuir ◽  
1998 ◽  
Vol 14 (12) ◽  
pp. 3255-3263 ◽  
Author(s):  
J. Wang ◽  
B. A. Bansenauer ◽  
B. E. Koel
Keyword(s):  
Methyl Nitrite

Nitro–Nitrite Isomerization and Transition State Switching in the Dissociation of Ionized Nitromethane: A Threshold Photoelectron–Photoion Coincidence Spectroscopy Study

2009 ◽  
Vol 15 (2) ◽  
pp. 157-166 ◽  
Author(s):  
Brandon Ferrier ◽  
Anne-Marie Boulanger ◽  
David M.P. Holland ◽  
David A. Shaw ◽  
Paul M. Mayer
Keyword(s):  
Transition State ◽  
Ab Initio Calculations ◽  
Ab Initio ◽  
Bond Cleavage ◽  
Cleavage Reaction ◽  
Nitrite Ion ◽  
Methyl Nitrite ◽  
Bond Cleavage Reaction ◽  
Entropy Of Activation ◽  
Lower Entropy

Threshold photoelectron–photoion coincidence (TPEPICO) spectroscopy has been employed to investigate the competition between bond cleavage and rearrangement reactions in the dissociation of ionized nitromethane, 1. Modeling TPEPICO breakdown diagrams with a combination of RRKM theory and ab initio calculations at the G3 level of theory allowed the derivation of the activation energy for the isomerisation of 1 to ionized methyl nitrite, 2, 82 kJ mol−1. In addition, evidence was found for a transition state switch in the bond cleavage reaction in 1 leading to CH3• + NO2+. As internal energy increases, the effective transition state for this reaction becomes tighter (i.e. is characterized by a lower entropy of activation, Δ‡S). Fitted thresholds for NO+ and CH2OHO+ ions, originating from the isomeric methyl nitrite ion, are consistent with G3 level ab initio calculations.

Active Pd(ii) complexes: enhancing catalytic activity by ligand effect for carbonylation of methyl nitrite to dimethyl carbonate

2017 ◽  
Vol 7 (17) ◽  
pp. 3785-3790 ◽  
Author(s):  
Hong-Zi Tan ◽  
Zhi-Qiao Wang ◽  
Zhong-Ning Xu ◽  
Jing Sun ◽  
Zhe-Ning Chen ◽  
...  
Keyword(s):  
Catalytic Activity ◽  
Dimethyl Carbonate ◽  
Ligand Effect ◽  
Methyl Nitrite ◽  
Catalytic Activities

The catalytic activities of Pd(ii) complexes for carbonylation of methyl nitrite to dimethyl carbonate could be enhanced by ligand effect.

Formation of methyl nitrite in engines fueled with gasoline/methanol and methanol/diesel

1982 ◽  
Vol 16 (2) ◽  
pp. 106-110 ◽  
Author(s):  
Anders. Jonsson ◽  
Britt Marie. Bertilsson
Keyword(s):  
Methyl Nitrite

Toxicity of Methyl Nitrite

1964 ◽  
Vol 14 (1) ◽  
pp. 24-25 ◽  
Author(s):  
W.G.F. Adams
Keyword(s):  
Methyl Nitrite

Insights into the Pd nanocatalysts directed by morphology effect for CO and methyl nitrite coupling to dimethyl oxalate

2020 ◽  
Vol 490 ◽  
pp. 110949
Author(s):  
Yaqi Qu ◽  
Yan Wang ◽  
Jianwei Li ◽  
Qiuxia Xu ◽  
Xin Liang ◽  
...  
Keyword(s):  
Methyl Nitrite ◽  
Dimethyl Oxalate ◽  
Morphology Effect
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