Emulsion Intercalation of Smectite Clays with Comb-Branched Copolymers Consisting of Multiple Quaternary Amine Salts and a Poly(styrene−butadiene−styrene) Backbone

Langmuir ◽  
2005 ◽  
Vol 21 (15) ◽  
pp. 7023-7028 ◽  
Author(s):  
Yu-Chung Chang ◽  
Chih-Cheng Chou ◽  
Jiang-Jen Lin
Keyword(s):  
Quaternary Amine ◽  
Branched Copolymers ◽  
Smectite Clays ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene ◽  
Amine Salts

TUNING PROPERTIES AND MORPHOLOGY IN HIGH VINYL CONTENT SBS BLOCK COPOLYMER, A THERMOPLASTIC ELASTOMER VIA THIOL-ENE MODIFICATION

2017 ◽  
Vol 90 (3) ◽  
pp. 550-561 ◽  
Author(s):  
Prithwiraj Mandal ◽  
Siva Ponnupandian ◽  
Soumyadip Choudhury ◽  
Nikhil K. Singha
Keyword(s):  
Block Copolymer ◽  
Thermoplastic Elastomer ◽  
Atomic Force Microscopy Analysis ◽  
Ene Reaction ◽  
Force Microscopy ◽  
Atomic Force ◽  
Microscopy Analysis ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

ABSTRACT Thiol-ene modification of high vinyl content thermoplastic elastomeric styrene butadiene styrene (SBS) block copolymer (BCP) was carried out using different thiolating agents in toluene at 70 °C. 1H NMR analysis confirmed the participation of vinyl double bond in the thiol-ene modification reaction of SBS. Surface morphology of the block copolymers evaluated by atomic force microscopy analysis showed higher roughness after the thiol-ene reaction. The thiol-modified SBS block copolymer showed better adhesion strength and oil resistance properties than the pristine SBS.

scholarly journals Evaluation of Properties and Micro-Characteristics of Waste Polyurethane/Styrene-Butadiene-Styrene Composite Modified Asphalt

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2249
Author(s):  
Bei Chen ◽  
Fuqiang Dong ◽  
Xin Yu ◽  
Changjiang Zheng
Keyword(s):  
Low Temperature ◽  
Performance Test ◽  
Permanent Deformation ◽  
Modified Asphalt ◽  
Basic Performance ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Sbs Modified Asphalt ◽  
And Storage ◽  
Butadiene Styrene

In order to solve the problems caused by asphalt diseases and prolong the life cycle of asphalt pavement, many studies on the properties of modified asphalt have been conducted, especially polyurethane (PU) modified asphalt. This study is to replace part of the styrene-butadiene-styrene (SBS) modifier with waste polyurethane (WP), for preparing WP/SBS composite modified asphalt, as well as exploring its properties and microstructure. On this basis, this paper studied the basic performance of WP/SBS composite modified asphalt with a conventional performance test, to analyze the high- and low-temperature rheological properties, permanent deformation resistance and storage stability of WP/SBS composite modified asphalt by dynamic shear rheometer (DSR) and bending beam rheometer (BBR) tests. The microstructure of WP/SBS composite modified asphalt was also observed by fluorescence microscope (FM) and Fourier transform infrared spectroscopy (FTIR), as well as the reaction between WP and asphalt. According to the results of this study, WP can replace SBS as a modifier to prepare WP/SBS composite modified asphalt with good low-temperature resistance, whose high-temperature performance will be lower than that of SBS modified asphalt. After comprehensive consideration, 4% SBS content and 15% WPU content (4 S/15 W) are determined as the suitable types of WPU/SBS composite modified asphalt.

Thermo‐responsive shape memory properties based on polylactic acid and styrene‐butadiene‐styrene block copolymer

2021 ◽  
pp. 51000
Author(s):  
Fathin Hani Azizul Rahim ◽  
Abdul Aziz Saleh ◽  
Raa Khimi Shuib ◽  
Ku Marsilla Ku Ishak ◽  
Zuratul Ain Abdul Hamid ◽  
...  
Keyword(s):  
Block Copolymer ◽  
Shape Memory ◽  
Polylactic Acid ◽  
Shape Memory Properties ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

Toughening of Polypropylene-Ethylene Copolymer with Nanosized CaCO3 and Styrene-Butadiene-Styrene

2007 ◽  
Vol 121-123 ◽  
pp. 1451-1454
Author(s):  
Jian Feng Chen ◽  
Guo Quan Wang ◽  
Xiao Fei Zeng ◽  
Hong Ying Zhao
Keyword(s):  
Average Particle Size ◽  
Average Particle ◽  
Single Screw Extruder ◽  
Roll Mill ◽  
The Matrix ◽  
Ethylene Copolymer ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
The Impact ◽  
Butadiene Styrene

Nanocomposites of nanosized-CaCO3/polypropylene-ethylene copolymer (PPE) and nanosized CaCO3/ PPE/ styrene-butadiene-styrene (SBS) were prepared by using two-roll mill and single screw extruder. The average particle size of nanosized CaCO3 was determined to be about 30 nm. By adding nanosized CaCO3 into PPE matrix, the toughness of the matrix improves significantly. At nanosized CaCO3 content of 12 phr (parts per hundred PPE resin by weight), the impact strength of CaCO3/PPE at room temperature reaches 61.6 KJ/m2, which is 3.02 times that of unfilled PPE matrix. In addition, the synergistic toughening effect of nanosized CaCO3 and SBS particles on PPE matrix was investigated.

Effect of styrene–butadiene–styrene content on the adhesion properties of bitumen before and after heat aging

2008 ◽  
Vol 35 (5) ◽  
pp. 454-460 ◽  
Author(s):  
Krzysztof Zieliński
Keyword(s):  
Adhesion Strength ◽  
Test Results ◽  
Adhesion Properties ◽  
Before And After ◽  
Styrene Content ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Steel Substrates ◽  
Butadiene Styrene

This article describes the effect of heat aging and styrene–butadiene–styrene (SBS) content in bitumen on the adhesion properties of mastics (bitumen-filler mix) to concrete and steel substrates. Test results showed that the adhesion strength of bituminous mastics to concrete and steel substrates decreased as the SBS content increased. Bitumen types modified with 9%–12% of SBS, commonly used in waterproofing materials, showed an approximately three times weaker bond with concrete and steel substrates than the nonmodified equivalents. Results also showed that after heat aging, the adhesion strength of the nonmodified bitumen was always higher than that of the unheated bitumen modified with 9%–12% of SBS.

The modification of bitumen with styrene–butadiene–styrene, ethylene vinyl acetate and varying the amount of reactive ethylene terpolymer

2017 ◽  
Vol 50 (3) ◽  
pp. 241-255 ◽  
Author(s):  
Seyfullah Keyf
Keyword(s):  
Vinyl Acetate ◽  
Softening Point ◽  
Elastic Recovery ◽  
Ethylene Vinyl Acetate ◽  
Modified Bitumen ◽  
Penetration Index ◽  
Different Types ◽  
Styrene Butadiene Styrene ◽  
Styrene Butadiene ◽  
Butadiene Styrene

In this article, 50/70 penetration grade TUPRAS bitumen was modified. Reactive elastomeric terpolymer (Elvaloy RET; DuPont Company), ethylene vinyl acetate (EVA) and styrene–butadiene–styrene (SBS) polymers were used in bitumen modification. Set hours of the tests were applied to samples taken from the obtained modified bitumen mixture. Varying amount of reactive ethylene terpolymer with weight ratios of 0.5%, 1.0%, 1.5%, 2.0% and 2.5% were introduced to the mixture of raw bitumen with 1.0% SBS and 1.0% EVA. Penetration, penetration index, softening point, ductility and elastic recovery tests were performed with these modified bitumen and raw bitumen. The samples of raw bitumen and modified bitumens of 2.0% Elvaloy RET, 1.0% SBS and 1.0% EVA were investigated by means of IR spectroscopy. The raw bitumen was modified with SBS, EVA and RET, and it was determined that penetration and ductility values were decreased while penetration index, softening point and elastic recovery were increased. The purpose of this study is to research the improving properties of 50/70 penetration grade–modified bitumen used in highways of Turkey. The most important characteristics (such as softening point, penetration and % elastic recovery) of new polymer-modified bitumen (NPMB) containing 2.5% EVA, 1% RET and 1% SBS were compared with eight different types of polymer-modified bitumens in Turkey (TPMB). NPMB provided all required parameters (softening point, penetration and % elastic recovery) for five different types of TPMBs (TPMB 70-16, TPMB 70-22, TPMB 76-16, TPMB 76-22 and TPMB 82-16).

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