Water-Soluble Poly(ferrocenylsilanes) for Supramolecular Assemblies by Layer-by-Layer Deposition

Langmuir ◽  
2002 ◽  
Vol 18 (20) ◽  
pp. 7629-7634 ◽  
Author(s):  
Mark A. Hempenius ◽  
Mária Péter ◽  
Neil S. Robins ◽  
E. Stefan Kooij ◽  
G. Julius Vancso
Keyword(s):  
Supramolecular Assemblies ◽  
Water Soluble ◽  
Layer By Layer ◽  
Layer Deposition ◽  
Soluble Poly

Water-Soluble Polyferrocenylsilanes for Supramolecular Assemblies by Layer-By-Layer Deposition

2003 ◽  
pp. 99-114
Author(s):  
Mark A. Hempenius ◽  
Mária Péter ◽  
Neil S. Robins ◽  
E. Stefan Kooij ◽  
Rob G. H. Lammertink ◽  
...  
Keyword(s):  
Supramolecular Assemblies ◽  
Water Soluble ◽  
Layer By Layer ◽  
Layer Deposition

scholarly journals Nanoparticle-Doped Hybrid Polyelectrolyte Microcapsules with Controlled Photoluminescence for Potential Bioimaging Applications

Polymers ◽  
2021 ◽  
Vol 13 (23) ◽  
pp. 4076
Author(s):  
Galina Nifontova ◽  
Victor Krivenkov ◽  
Mariya Zvaigzne ◽  
Anton Efimov ◽  
Evgeny Korostylev ◽  
...  
Keyword(s):  
Semiconductor Nanocrystals ◽  
Emission Spectra ◽  
Fluorescent Imaging ◽  
Water Soluble ◽  
Layer By Layer ◽  
Layer Deposition ◽  
Theranostic Agents ◽  
Further Development ◽  
Oppositely Charged ◽  
Transformation Processes

Fluorescent imaging is widely used in the diagnosis and tracking of the distribution, interaction, and transformation processes at molecular, cellular, and tissue levels. To be detectable, delivery systems should exhibit a strong and bright fluorescence. Quantum dots (QDs) are highly photostable fluorescent semiconductor nanocrystals with wide absorption spectra and narrow, size-tunable emission spectra, which make them suitable fluorescent nanolabels to be embedded into microparticles used as bioimaging and theranostic agents. The layer-by-layer deposition approach allows the entrapping of QDs, resulting in bright fluorescent microcapsules with tunable surface charge, size, rigidity, and functional properties. Here, we report on the engineering and validation of the structural and photoluminescent characteristics of nanoparticle-doped hybrid microcapsules assembled by the deposition of alternating oppositely charged polyelectrolytes, water-soluble PEGylated core/shell QDs with a cadmium selenide core and a zinc sulfide shell (CdSe/ZnS), and carboxylated magnetic nanoparticles (MNPs) onto calcium carbonate microtemplates. The results demonstrate the efficiency of the layer-by-layer approach to designing QD-, MNP-doped microcapsules with controlled photoluminescence properties, and pave the way for the further development of next-generation bioimaging agents based on hybrid materials for continuous fluorescence imaging.

Hybrid photovoltaic cells with II–VI quantum dot sensitizers fabricated by layer-by-layer deposition of water-soluble components

2009 ◽  
Vol 518 (1) ◽  
pp. 295-298 ◽  
Author(s):  
Rolf Kniprath ◽  
Jürgen P. Rabe ◽  
James T. McLeskey ◽  
Dayang Wang ◽  
Stefan Kirstein
Keyword(s):  
Quantum Dot ◽  
Photovoltaic Cells ◽  
Water Soluble ◽  
Layer By Layer ◽  
Layer Deposition ◽  
Soluble Components

Heterojunction of Hydrophobic Poly(1,4-phenylenevinylene) and Hydrophilic PEDOT:PSS on Hydrophilic CdS Nanoparticles

2008 ◽  
Vol 8 (9) ◽  
pp. 4730-4733 ◽  
Author(s):  
Wonjoo Lee ◽  
Su Jin Baek ◽  
Sun Ki Min ◽  
Gangri Cai ◽  
Joong Ki Lee ◽  
...  
Keyword(s):  
Thermal Treatment ◽  
Water Soluble ◽  
Cds Nanoparticles ◽  
Layer By Layer ◽  
Deposition Method ◽  
Water Contact ◽  
Styrene Sulfonate ◽  
Layer Deposition ◽  
Poly Styrene Sulfonate ◽  
Positively Charged

Heterojunction of hydrophobic poly(1,4-phenylenevinylene) (PPV) on hydrophilic CdS nanoparticles was successfully prepared by the multi-layering of poly(p-xylene tetrahydrothiophenium chloride) (pre-PPV: precursor of PPV polymer) and poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT:PSS) in an aqueous solution followed by a thermal treatment. CdS nanoparticles thin films were prepared on tin-doped indium oxide (ITO) by a chemical-bath-deposition method. The CdS surface was hydrophilic with low water contact angle of 15°. Positively charged and water-soluble pre-PPV was used to form multilayers with PEDOT:PSS by a layer-by-layer deposition method. Pre-PPV is easily converted to conjugated PPV polymer by a thermal treatment. The CdS nanoparticles-(PPV/PEDOT:PSS) multilayer films constitute efficient acceptor-sensitizer dyad systems, which generate a photocurrent of 2,660 nA/cm2 under the air mass (AM) 1.5 conditions (I = 100 mW/cm2) for sample with 4.5 bilayers.

Layer‐by‐layer assembly and electrically controlled disassembly of water‐soluble Poly(3,4‐ethylenedioxythiophene) derivatives for bioelectronic interface

2020 ◽  
Vol 67 (9) ◽  
pp. 1602-1610
Author(s):  
Bhaskarchand Gautam ◽  
Hailemichael Ayalew ◽  
Udesh Dhawan ◽  
Jayakrishnan Aerathupalathu Janardhanan ◽  
Hsiao‐hua Yu
Keyword(s):  
Water Soluble ◽  
Layer By Layer ◽  
Layer By Layer Assembly ◽  
Layer Assembly ◽  
Soluble Poly

Radical-triggered cross-linking for molecular layer deposition of SiAlCOH hybrid thin films

2021 ◽  
Author(s):  
Kristina Ashurbekova ◽  
Karina Ashurbekova ◽  
Iva Saric ◽  
Evgeny Modin ◽  
Mladen Petravic ◽  
...  
Keyword(s):  
Thin Film ◽  
Film Growth ◽  
Molecular Layer ◽  
Thin Film Growth ◽  
Cross Linking ◽  
Layer By Layer ◽  
Molecular Layer Deposition ◽  
Layer Deposition ◽  
Hybrid Thin Films ◽  
Enhanced Stability

We developed a thin film growth with a radical-initiated cross-linking of vinyl groups in a layer-by-layer manner via molecular layer deposition (MLD). The cross-linked film exhibited improved properties like 12% higher density and enhanced stability compared to the non-cross-linked film.

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