n-Nonane preadsorption as a tool to understand the mechanism of carbon dioxide adsorption in activated carbons

Langmuir ◽  
1993 ◽  
Vol 9 (11) ◽  
pp. 3317-3319 ◽  
Author(s):  
J. M. Martin-Martinez ◽  
M. C. Mittelmeijer-Hazeleger
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbons ◽  
Carbon Dioxide Adsorption

Adsorption cooling cycles: Insights into carbon dioxide adsorption on activated carbons

Energy ◽  
2016 ◽  
Vol 102 ◽  
pp. 491-501 ◽  
Author(s):  
Wu Fan ◽  
Anutosh Chakraborty ◽  
Sibnath Kayal
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbons ◽  
Carbon Dioxide Adsorption

Carbon Dioxide Adsorption Isotherms on Activated Carbons

2011 ◽  
Vol 56 (5) ◽  
pp. 1974-1981 ◽  
Author(s):  
Bidyut Baran Saha ◽  
Skander Jribi ◽  
Shigeru Koyama ◽  
Ibrahim I. El-Sharkawy
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Isotherms ◽  
Activated Carbons ◽  
Carbon Dioxide Adsorption

scholarly journals Utilization of spent dregs for the production of activated carbon for CO2 adsorption

2017 ◽  
Vol 19 (2) ◽  
pp. 44-50 ◽  
Author(s):  
Jarosław Serafin
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbon ◽  
Density Functional ◽  
Activated Carbons ◽  
Density Functional Theory Method ◽  
Textural Properties ◽  
Carbon Dioxide Adsorption ◽  
Functional Theory ◽  
Surface Areas ◽  
Adsorption Desorption

Abstract The objective of this work was preparation of activated carbon from spent dregs for carbon dioxide adsorption. A saturated solution of KOH was used as an activating agent. Samples were carbonized in the furnace at the temperature of 550°C. Textural properties of activated carbons were obtained based on the adsorption-desorption isotherms of nitrogen at −196°C and carbon dioxide at 0°C. The specific surface areas of activated carbons were calculated by the Brunauer – Emmett – Teller equation. The volumes of micropores were obtained by density functional theory method. The highest CO2 adsorption was 9.54 mmol/cm3 at 0°C – and 8.50 mmol/cm3 at 25°C.

Applicability of the Dubinin-Radushkevich equation to carbon dioxide adsorption on activated carbons

Langmuir ◽  
1993 ◽  
Vol 9 (11) ◽  
pp. 2758-2760 ◽  
Author(s):  
F. Carrasco-Marin ◽  
M. V. Lopez-Ramon ◽  
C. Moreno-Castilla
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbons ◽  
Carbon Dioxide Adsorption

Optimizing the properties of granular walnut-shell based KOH activated carbons for carbon dioxide adsorption

2017 ◽  
Vol 21 ◽  
pp. 436-443 ◽  
Author(s):  
Katarzyna Chomiak ◽  
Stanisław Gryglewicz ◽  
Krzysztof Kierzek ◽  
Jacek Machnikowski
Keyword(s):  
Carbon Dioxide ◽  
Activated Carbons ◽  
Walnut Shell ◽  
Carbon Dioxide Adsorption

Influence of intramolecular interactions on carbon dioxide gas adsorption capacity in Mesoporous Imine polymers

2018 ◽  
Author(s):  
Jaya Prakash Madda ◽  
Pilli Govindaiah ◽  
Sushant Kumar Jena ◽  
Sabbhavat Krishna ◽  
Rupak Kishor
Keyword(s):  
Carbon Dioxide ◽  
Adsorption Capacity ◽  
Density Functional ◽  
Gas Adsorption ◽  
Ambient Pressure ◽  
Condensation Reaction ◽  
Intramolecular Interactions ◽  
Carbon Dioxide Adsorption ◽  
Nitrogen Gas ◽  
Adsorption Characteristic

<p>Covalent organic Imine polymers with intrinsic meso-porosity were synthesized by condensation reaction between 4,4-diamino diphenyl methane and (para/meta/ortho)-phthaladehyde. Even though these polymers were synthesized from precursors of bis-bis covalent link mode, the bulk materials were micrometer size particles with intrinsic mesoporous enables nitrogen as well as carbon dioxide adsorption in the void spaces. These polymers were showed stability up to 260<sup>o</sup> centigrade. Nitrogen gas adsorption capacity up to 250 cc/g in the ambient pressure was observed with type III adsorption characteristic nature. Carbon dioxide adsorption experiments reveal the possible terminal amine functional group to carbamate with CO<sub>2</sub> gas molecule to the polymers. One of the imine polymers, COP-3 showed more carbon dioxide sorption capacity and isosteric heat of adsorption (Q<sub>st</sub>) than COP-1 and COP-2 at 273 K even though COP-3 had lower porosity for nitrogen gas than COP-1 and COP-2. We explained the trends in gas adsorption capacities and Qst values as a consequence of the intra molecular interactions confirmed by Density Functional Theory computational experiments on small molecular fragments.</p>

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