Study of adsorption from dilute solutions. Thermodynamic analysis of experimental data

Langmuir ◽  
1994 ◽  
Vol 10 (2) ◽  
pp. 563-569 ◽  
Author(s):  
M. Nagy
Keyword(s):  
Experimental Data ◽  
Thermodynamic Analysis ◽  
Dilute Solutions

scholarly journals Thermodynamic analysis of synthesis of cyclopentanol from cyclopentene and comparison with experimental data

2015 ◽  
Vol 5 (2) ◽  
pp. 135-142 ◽  
Author(s):  
Benzhen Yao ◽  
Zhiqing Wang ◽  
Tiancun Xiao ◽  
Fahai Cao ◽  
Peter P. Edwards ◽  
...  
Keyword(s):  
Experimental Data ◽  
Thermodynamic Analysis ◽  
Comparison With Experimental Data

Solubility of celecoxib in 1-propanol + water mixtures at T= (293.2–313.2) K: experimental data and thermodynamic analysis

2018 ◽  
Vol 58 (2) ◽  
pp. 175-183 ◽  
Author(s):  
Esmail Mohammadian ◽  
Elaheh Rahimpour ◽  
Mohammad Barzegar-Jalali ◽  
Sina Dadmand ◽  
Fleming Martinez ◽  
...  
Keyword(s):  
Experimental Data ◽  
Thermodynamic Analysis

The Conductance of Sodium Perchlorate in Water-sulfolane Mixtures at 35 °C

1975 ◽  
Vol 30 (4) ◽  
pp. 533-536 ◽  
Author(s):  
Giuseppe Petrella ◽  
Maurizio Castagnolo ◽  
Antonio Sacco
Keyword(s):  
Experimental Data ◽  
Sodium Chloride ◽  
Composition Range ◽  
Sodium Perchlorate ◽  
Ion Association ◽  
Transport Numbers ◽  
Aprotic Solvents ◽  
Solvent Mixtures ◽  
Dilute Solutions ◽  
Protic Solvents

Abstract Measurements on the conductance of dilute solutions of sodium Perchlorate, at 35 °C, in water-sulfolane mixtures over the entire solvent composition range are reported. Experimental data were analyzed by the 1965 Fuoss-Onsager-Skinner equations.No detectable ion association was found for this electrolyte, unlike sodium chloride in the same solvent mixtures. The association order KA(Cl-)>KA(ClO4-) is in contrast with that observed in protic solvents [KA(ClO4-)>KA(Cl-)] and is similar to that found in aprotic solvents. This shows that in water-sulfolane mixtures, association phenomena are mainly controlled by sulfolane.The lack of transport numbers for water-sulfolane mixtures precludes unambiguous explanations for Waiden products A0η.

Thermodynamic Analysis of the Fe-Mn-P Ternary Phase Diagram by Combining the First-Principles and CALPHAD Methods

2007 ◽  
Vol 561-565 ◽  
pp. 1899-1902 ◽  
Author(s):  
T. Tokunaga ◽  
N. Hanaya ◽  
Hiroshi Ohtani ◽  
Mitsuhiro Hasebe
Keyword(s):  
Experimental Data ◽  
Phase Diagram ◽  
Ternary System ◽  
Thermodynamic Analysis ◽  
First Principles ◽  
Binary Systems ◽  
Ternary Phase ◽  
Ternary Phase Diagram ◽  
First Principles Calculations ◽  
The Enthalpy Of Formation

A thermodynamic analysis of the Fe-Mn-P ternary system has been carried out using the CALPHAD method. Among the three binary systems relevant to this ternary phase diagram, the thermodynamic parameters of the Mn-P binary system were evaluated in this study. The enthalpy of formation of the binary phosphides obtained from our first-principles calculations was utilized in the present analysis to compensate for the lack of available experimental data. The thermodynamic descriptions of the Fe-Mn and Fe-P binary systems were taken from previous studies. The phase equilibria in the Fe-Mn-P ternary system were analysed based on the experimental data on the phase boundaries. The calculated phase diagrams are in agreement with the experimental results.

scholarly journals Thermodynamic Analysis of the Defective Subsystem of Lead Telluride Crystals with Impurity of Oxygen

2019 ◽  
Vol 20 (1) ◽  
pp. 40-45
Author(s):  
V. Prokopiv ◽  
I. Horichok ◽  
T. Semko ◽  
R. Dzumedzey ◽  
G. Mateik ◽  
...  
Keyword(s):  
Experimental Data ◽  
Seebeck Coefficient ◽  
Hall Effect ◽  
Thermodynamic Analysis ◽  
Specific Conductivity ◽  
Lead Telluride ◽  
Electrophysical Properties ◽  
Heat Treated

Electrophysical properties (specific conductivity, Seebeck coefficient, Hall effect) of the lead telluride obtained by pressing of the powder were investigated. In this case, the powder was pre-heat treated at 300 oC in the air to saturate it with oxygen. To interpret the experimental data obtained, a model of a defect subsystem of crystals of lead telluride with impurity of oxygen is proposed.

Measurement of Latent Heat by the Gas-Current Method

1942 ◽  
Vol 9 (1) ◽  
pp. A21-A25
Author(s):  
J. A. Goff ◽  
J. B. Hunter
Keyword(s):  
Experimental Data ◽  
Water Vapor ◽  
Latent Heat ◽  
Thermodynamic Analysis ◽  
Current Method ◽  
Interaction Constant ◽  
University Of Pennsylvania ◽  
Scientific School ◽  
Vapor Mixtures ◽  
American Society

Abstract The gas-current method of measuring latent heat appears to possess important advantages over other calorimetric methods. Preliminary results have been derived from a co-operative investigation carried out by the American Society of Heating and Ventilating Engineers and the Towne Scientific School, University of Pennsylvania, in which sufficiently reliable values of the interaction constant for air-and-water-vapor mixtures have been determined to permit an adequate thermodynamic analysis of the gas-current method. The present paper is devoted to the development of this analysis and its application to the reduction of certain experimental data recently obtained by one of the authors. The apparatus and method of conducting the experiments are also described.

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