Impacts of the Carbonyl Group Location of Ester Bond on Interfacial Properties of Sugar-Based Surfactants: Experimental and Computational Evidences

2009 ◽  
Vol 113 (26) ◽  
pp. 8872-8877 ◽  
Author(s):  
Hary Razafindralambo ◽  
Christophe Blecker ◽  
Samir Mezdour ◽  
Claude Deroanne ◽  
Jean-Marc Crowet ◽  
...  
Keyword(s):  
Carbonyl Group ◽  
Interfacial Properties ◽  
Ester Bond

Interfacial properties of GaSb/InAs superlattices

1993 ◽  
Vol 51 ◽  
pp. 826-827
Author(s):  
M. E. Twigg ◽  
B. R. Bennett ◽  
J. R. Waterman ◽  
J. L. Davis ◽  
B. V. Shanabrook ◽  
...  
Keyword(s):  
Gaas Substrate ◽  
Molecular Beam ◽  
Infrared Detector ◽  
Interfacial Properties ◽  
Ex Situ ◽  
X Ray Diffraction ◽  
Absorption Coefficients ◽  
X Ray ◽  
Short Period ◽  
High Optical Absorption

Recently, the GaSb/InAs superlattice system has received renewed attention. The interest stems from a model demonstrating that short period Ga1-xInxSb/InAs superlattices will have both a band gap less than 100 meV and high optical absorption coefficients, principal requirements for infrared detector applications. Because this superlattice system contains two species of cations and anions, it is possible to prepare either InSb-like or GaAs-like interfaces. As such, the system presents a unique opportunity to examine interfacial properties.We used molecular beam epitaxy (MBE) to prepare an extensive set of GaSb/InAs superlattices grown on an GaSb buffer, which, in turn had been grown on a (100) GaAs substrate. Through appropriate shutter sequences, the interfaces were directed to assume either an InSb-like or GaAs-like character. These superlattices were then studied with a variety of ex-situ probes such as x-ray diffraction and Raman spectroscopy. These probes confirmed that, indeed, predominantly InSb-like and GaAs-like interfaces had been achieved.

Surface and Interfacial Properties of Mono and Didodecyl Diphenyl Ether Disulfonates

2018 ◽  
Vol 55 (4) ◽  
pp. 302-311
Author(s):  
Long Bai ◽  
Xiaochen Liu ◽  
Tiliu Jiao ◽  
Yong Wang ◽  
Yueqing Huo ◽  
...  
Keyword(s):  
Diphenyl Ether ◽  
Interfacial Properties

Synthesis and Surface/Interfacial Properties of Novel Dialkyl Disulfonate Gemini Surfactants Derived from 1,3,5-triazine

2016 ◽  
Vol 53 (6) ◽  
pp. 595-600 ◽  
Author(s):  
Ruixia Niu ◽  
Chao Wang ◽  
Hua Song ◽  
Jingling Wang ◽  
Daqiang Wang ◽  
...  
Keyword(s):  
Gemini Surfactants ◽  
Interfacial Properties

Interfacial Properties of Alkylbenzene Sulfonates Ternary Mixtures

2015 ◽  
Vol 52 (3) ◽  
pp. 252-255 ◽  
Author(s):  
Li Tang ◽  
Xiaochen Liu ◽  
Jinping Niu ◽  
Xiaoyu Wang
Keyword(s):  
Interfacial Properties ◽  
Ternary Mixtures

Surface and Interfacial Properties of InP

1985 ◽  
Author(s):  
L. G. Meiners ◽  
H. H. Wieder
Keyword(s):  
Interfacial Properties

Polarographic reduction of α-(4-ethylbenzoyl)-α,β-dibromopropionic acid on mercury dropping electrode

1979 ◽  
Vol 44 (4) ◽  
pp. 1318-1323
Author(s):  
Miloslava Počtová
Keyword(s):  
Electrochemical Reduction ◽  
Carbonyl Group ◽  
Polarographic Reduction ◽  
Polarographic Wave ◽  
Intermediate Products ◽  
Active Intermediate

A mechanism of the electrochemical reduction of β-(4-ethylbenzoyl)-α,β-dibromopropionic acid is suggested based on the results of classical polarography and polarography with Kalousek's switch and on the identification of the polarographically active intermediate products. The substance converts to β-4-ethylbenzoylacrylic acid on the electrochemical elimination of the bromine atoms, and the latter acid is reduced further to β-4-ethylbenzoylpropionic acid. The most negative polarographic wave corresponds to the reduction of the carbonyl group in the benzoyl part of the last acid.

119Sn, 13C and 1H NMR Spectra of Tris(1-butyl)stannyl D-Glucuronate

1997 ◽  
Vol 62 (8) ◽  
pp. 1169-1176 ◽  
Author(s):  
Antonín Lyčka ◽  
Jaroslav Holeček ◽  
David Micák
Keyword(s):  
Chemical Shift ◽  
Carbonyl Group ◽  
1H Nmr ◽  
Equatorial Plane ◽  
Title Compound ◽  
Nmr Spectra ◽  
Hydroxyl Groups ◽  
Carboxylic Group ◽  
H Nmr ◽  
Oxygen Atoms

The 119Sn, 13C and 1H NMR spectra of tris(1-butyl)stannyl D-glucuronate have been measured in hexadeuteriodimethyl sulfoxide, tetradeuteriomethanol and deuteriochloroform. The chemical shift values have been assigned unambiguously with the help of H,H-COSY, TOCSY, H,C-COSY and 1H-13C HMQC-RELAY. From the analysis of parameters of 119Sn, 13C and 1H NMR spectra of the title compound and their comparison with the corresponding spectra of tris(1-butyl)stannyl acetate and other carboxylates it follows that in solutions of non-coordinating solvents (deuteriochloroform) the title compound is present in the form of more or less isolated individual molecules with pseudotetrahedral environment around the central tin atom and with monodentately bound carboxylic group. The interaction of tin atom with oxygen atoms of carbonyl group and hydroxyl groups of the saccharide residue - if they are present at all - are very weak. In solutions in coordinating solvents (hexadeuteriodimethyl sulfoxide or tetradeuteriomethanol), the title compound forms complexes with one molecule of the solvent. Particles of these complexes have a shape of trigonal bipyramid with the 1-butyl substituents in equatorial plane and the oxygen atoms of monodentate carboxylic group and coordinating solvent in axial positions.

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