Study of the Adsorption of Organic Molecules on Transition Metal Exchanged Zeolites via Solid State NMR. Part 2: Adsorption of Organic Molecules on Zeolite NaX, CaX, and CaCoX

2008 ◽  
Vol 112 (32) ◽  
pp. 9630-9640 ◽  
Author(s):  
Kristof Houthoofd ◽  
Piet J. Grobet ◽  
Pierre A. Jacobs
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Organic Molecules ◽  
Zeolite Nax ◽  
Adsorption Of Organic Molecules

A strategy for acquisition and analysis of complex natural abundance 33S solid-state NMR spectra of a disordered tetrathio transition-metal anion

2010 ◽  
Vol 202 (2) ◽  
pp. 173-179 ◽  
Author(s):  
Hans J. Jakobsen ◽  
Henrik Bildsøe ◽  
Jørgen Skibsted ◽  
Michael Brorson ◽  
Peter Gor’kov ◽  
...  
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Natural Abundance ◽  
Metal Anion

Lithium transition metal pnictides – structural chemistry, electrochemistry, and function

2015 ◽  
Vol 35 (1) ◽  
pp. 1-24 ◽  
Author(s):  
Florian Winter ◽  
Rainer Pöttgen ◽  
Magnus Greiwe ◽  
Tom Nilges
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Crystal Structures ◽  
Chemical Bonding ◽  
Electrochemical Behavior ◽  
Solid State Nmr ◽  
Structural Chemistry ◽  
Covalently Bonded ◽  
Interesting Class ◽  
And Function

AbstractLithium-transition metal (T)-pnictides (Pn=P, As, Sb, Bi) are an interesting class of materials with greatly differing crystal structures. The transition metal and pnictide atoms build up covalently bonded networks that leave cavities or channels for the lithium atoms. Depending on the bonding of lithium to the polyanionic network, one observes mobility of the lithium atoms. The crystal chemistry, chemical bonding, 7Li solid-state NMR, and the electrochemical behavior of the pnictides are reviewed. The structural chemistry is compared with related tetrelides.

High-resolution solid-state NMR investigation of the nature of the interaction between organic substrates and the zeolite ZSM-5 lattice

1988 ◽  
Vol 66 (8) ◽  
pp. 1942-1947 ◽  
Author(s):  
C. A. Fyfe ◽  
H. Strobl ◽  
H. Gies ◽  
G. T. Kokotailo
Keyword(s):  
Solid State ◽  
High Resolution ◽  
Phase Change ◽  
Solid State Nmr ◽  
Organic Molecules ◽  
Lattice Structure ◽  
Model System ◽  
Mas Nmr ◽  
Organic Substrates ◽  
Nmr Spectrum

The compounds p-xylene, p-chlorotoluene, and p-dichlorobenzene induce essentially identical changes in the 29Si MAS NMR spectrum of zeolite ZSM-5, indicating that the major contribution to the induced phase change of the lattice structure in these cases is the size and shape of the sorbed organic molecules. Based on these results, p-dichlorobenzene may be used as a model system in future diffraction studies of the sorbate/lattice structure greatly facilitating these investigations.

Structure and surface reactivity of transition-metal–oxo–organo clusters: contribution of liquid- and solid-state NMR to the characterization of the cluster Ti16O16(OEt)32

2004 ◽  
Vol 7 (3-4) ◽  
pp. 241-248 ◽  
Author(s):  
Stéphanie Le Calvé ◽  
Bruno Alonso ◽  
Laurence Rozes ◽  
Clément Sanchez ◽  
Marie-Noëlle Rager ◽  
...  
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Surface Reactivity
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