Comparing Main Group and Transition-Metal Square-Planar Complexes of the Diselenoimidodiphosphinate Anion: A Solid-State NMR Investigation of M[N(iPr2PSe)2]2(M = Se, Te; Pd, Pt)

2008 ◽  
Vol 47 (7) ◽  
pp. 2786-2797 ◽  
Author(s):  
Bryan A. Demko ◽  
Roderick E. Wasylishen
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Main Group ◽  
Square Planar ◽  
Square Planar Complexes

A strategy for acquisition and analysis of complex natural abundance 33S solid-state NMR spectra of a disordered tetrathio transition-metal anion

2010 ◽  
Vol 202 (2) ◽  
pp. 173-179 ◽  
Author(s):  
Hans J. Jakobsen ◽  
Henrik Bildsøe ◽  
Jørgen Skibsted ◽  
Michael Brorson ◽  
Peter Gor’kov ◽  
...  
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Nmr Spectra ◽  
Natural Abundance ◽  
Metal Anion

Lithium transition metal pnictides – structural chemistry, electrochemistry, and function

2015 ◽  
Vol 35 (1) ◽  
pp. 1-24 ◽  
Author(s):  
Florian Winter ◽  
Rainer Pöttgen ◽  
Magnus Greiwe ◽  
Tom Nilges
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Crystal Structures ◽  
Chemical Bonding ◽  
Electrochemical Behavior ◽  
Solid State Nmr ◽  
Structural Chemistry ◽  
Covalently Bonded ◽  
Interesting Class ◽  
And Function

AbstractLithium-transition metal (T)-pnictides (Pn=P, As, Sb, Bi) are an interesting class of materials with greatly differing crystal structures. The transition metal and pnictide atoms build up covalently bonded networks that leave cavities or channels for the lithium atoms. Depending on the bonding of lithium to the polyanionic network, one observes mobility of the lithium atoms. The crystal chemistry, chemical bonding, 7Li solid-state NMR, and the electrochemical behavior of the pnictides are reviewed. The structural chemistry is compared with related tetrelides.

Anionic cyclometallated Pt(ii) square-planar complexes: new sets of highly luminescent compounds

2017 ◽  
Vol 46 (37) ◽  
pp. 12625-12635 ◽  
Author(s):  
Loredana Ricciardi ◽  
Massimo La Deda ◽  
Andreea Ionescu ◽  
Nicolas Godbert ◽  
Iolinda Aiello ◽  
...  
Keyword(s):  
Solid State ◽  
Emission Efficiency ◽  
Square Planar ◽  
Square Planar Complexes

Novel anionic Pt(ii) complexes were synthesized, displaying an outstanding enhancement of the emission efficiency in the solid state.

Structure and surface reactivity of transition-metal–oxo–organo clusters: contribution of liquid- and solid-state NMR to the characterization of the cluster Ti16O16(OEt)32

2004 ◽  
Vol 7 (3-4) ◽  
pp. 241-248 ◽  
Author(s):  
Stéphanie Le Calvé ◽  
Bruno Alonso ◽  
Laurence Rozes ◽  
Clément Sanchez ◽  
Marie-Noëlle Rager ◽  
...  
Keyword(s):  
Solid State ◽  
Transition Metal ◽  
Solid State Nmr ◽  
Surface Reactivity
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