Hierarchical Mordenite Dedicated to the Fluid Catalytic Cracking Process: Catalytic Performance Regarding Textural and Acidic Properties

2014 ◽  
Vol 118 (48) ◽  
pp. 28043-28054 ◽  
Author(s):  
Kinga Góra-Marek ◽  
Karolina Tarach ◽  
Justyna Tekla ◽  
Zbigniew Olejniczak ◽  
Piotr Kuśtrowski ◽  
...  
Fuel ◽  
2021 ◽  
Vol 292 ◽  
pp. 120364
Author(s):  
Peipei Miao ◽  
Xiaolin Zhu ◽  
Yangling Guo ◽  
Jie Miao ◽  
Mengyun Yu ◽  
...  

2005 ◽  
Vol 17 (9) ◽  
pp. 2466-2474 ◽  
Author(s):  
P. Kortunov ◽  
S. Vasenkov ◽  
J. Kärger ◽  
M. Fé Elía ◽  
M. Perez ◽  
...  

Teknik ◽  
2021 ◽  
Vol 42 (2) ◽  
pp. 218-225
Author(s):  
Rahma Amalia ◽  
Teguh Riyanto ◽  
Istadi Istadi

This work discusses the treated spent Residue Fluid Catalytic Cracking (RFCC) catalysts using sulfuric or citric acids to examine the impact of acid treatment on the catalyst physicochemical properties and structural characteristics. The catalysts were characterized by X-ray diffraction (XRD), X-ray fluorescence (XRF), and Brunauer−Emmett−Teller-Barrett−Joyner−Halenda (BET-BJH) methods. The catalytsts were performed in a continuous fixed-bed reactor for catalytic cracking of palm oil. Changes of the catalyst characteristics and catalytic performance testing of the catalyst after the acid treatment for palm oil cracking process were discussed. It was found that the acid treatment on the spent RFCC catalyst can increase the surface area and pore volume of catalysts as well as the crystallinity. The closed pores in the spent RFCC are opened by acid treatment by eliminating heavy metals. Concerning to the catalytic performance, the acid-treated catalysts had better performance than the non-treated catalyst, which could increase selectivity of the kerosene-diesel range fraction from 47.89% to 55.41%. It was interested, since the non-treated catalyst could not produce gasoline fraction, while the acid-treated catalsysts could produce gasoline fraction at selectivity range of 0.57 – 0.84%. It was suggested that both sulfuric or citric acids treatment could increase the cracking performance of spent RFCC catalyst by shifting the product to lower hydrocarbons.


2013 ◽  
Vol 1 ◽  
pp. 194308921350702
Author(s):  
Madhavi Madeti ◽  
Sharad V. Lande ◽  
Kalpana G ◽  
R. K. Mewada ◽  
R. V. Jasra

We have attempted a green alternative to reuse the spent fluid catalytic cracking (FCC) catalyst that is used in petroleum refining industry for the upgradation and purification of various petroleum streams and residues. The spent FCC zeolite–based catalyst modified by enhancing the acidic properties by incorporating Zn and In metals in the matrix. The various prepared catalysts were systematically characterized by X-ray powder diffraction and Brunauer–Emmett–Teller (BET; adsorption isotherm) surface area. The acidity of the materials was studied by temperature-programmed desorption of ammonia (NH3-TPD). The well-characterized catalysts were applied for liquid phase benzylation of o-xylene using benzyl chloride.


2014 ◽  
Vol 4 (4) ◽  
pp. 389-394
Author(s):  
Hao Song ◽  
Zhen Liu ◽  
Wei Xing ◽  
Rui Feng ◽  
Zifeng Yan ◽  
...  

2014 ◽  
Vol 4 (4) ◽  
pp. 395-400 ◽  
Author(s):  
Jinhong Zhang ◽  
Honghong Shan ◽  
Xiaobo Chen ◽  
Chunyi Li ◽  
Chaohe Yang

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