Hydrolysis of Glyoxal in Water-Restricted Environments: Formation of Organic Aerosol Precursors through Formic Acid Catalysis

2014 ◽  
Vol 118 (23) ◽  
pp. 4095-4105 ◽  
Author(s):  
Montu K. Hazra ◽  
Joseph S. Francisco ◽  
Amitabha Sinha
Keyword(s):  
Formic Acid ◽  
Acid Catalysis ◽  
Organic Aerosol ◽  
Hydrolysis Of

Acid-catalyzed Solvolysis of Isonitriles. I

1971 ◽  
Vol 49 (14) ◽  
pp. 2455-2459 ◽  
Author(s):  
Y. Y. Lim ◽  
A. R. Stein
Keyword(s):  
Formic Acid ◽  
Acid Catalysis ◽  
Hydrolysis Product ◽  
Rate Dependence ◽  
Linear Rate ◽  
First Order ◽  
Methyl Amine ◽  
Acid Catalyzed ◽  
Pseudo First Order ◽  
Hydrolysis Of

The acid-catalyzed hydrolysis of methyl isonitrile has been examined. The initial hydrolysis product is N-methylformamide which is further hydrolyzed to methyl amine and formic acid at a much slower rate. The hydrolysis to N-methylformamide is pseudo-first order in methyl isonitrile and shows a linear rate dependence on concentration of general (buffer) acid at fixed pH. The significance of general acid-catalysis in terms of the mechanism of the hydrolysis is considered and taken as evidence for carbon protonation rather than nitrogen protonation as the initiating step.

Gas Phase Hydrolysis of Formaldehyde To Form Methanediol: Impact of Formic Acid Catalysis

2013 ◽  
Vol 117 (46) ◽  
pp. 11704-11710 ◽  
Author(s):  
Montu K. Hazra ◽  
Joseph S. Francisco ◽  
Amitabha Sinha
Keyword(s):  
Formic Acid ◽  
Gas Phase ◽  
Acid Catalysis ◽  
Hydrolysis Of

Hydrolysis of Ketene Catalyzed by Formic Acid: Modification of Reaction Mechanism, Energetics, and Kinetics with Organic Acid Catalysis

2015 ◽  
Vol 119 (19) ◽  
pp. 4347-4357 ◽  
Author(s):  
Matthew K. Louie ◽  
Joseph S. Francisco ◽  
Marco Verdicchio ◽  
Stephen J. Klippenstein ◽  
Amitabha Sinha
Keyword(s):  
Reaction Mechanism ◽  
Formic Acid ◽  
Organic Acid ◽  
Acid Catalysis ◽  
Acid Modification ◽  
Hydrolysis Of

Nonenzymatic Hydrolysis of Cocainevia Intramolecular Acid Catalysis

1999 ◽  
Vol 82 (1) ◽  
pp. 85-89 ◽  
Author(s):  
Pan Li ◽  
Kang Zhao ◽  
Shixian Deng ◽  
Donald W. Landry
Keyword(s):  
Acid Catalysis ◽  
Hydrolysis Of

scholarly journals Mechanism and theory of d-glucopyranose homogeneous acid catalysis in the aqueous solution phase

2019 ◽  
Vol 21 (32) ◽  
pp. 17993-18011 ◽  
Author(s):  
Manik Kumer Ghosh ◽  
Mícheál Séamus Howard ◽  
Karla Dussan ◽  
Stephen Dooley
Keyword(s):  
Aqueous Solution ◽  
Acid Hydrolysis ◽  
Acid Catalysis ◽  
Theoretical Study ◽  
Solution Phase ◽  
Homogeneous Acid ◽  
Hydrolysis Of

Theoretical study of the mechanism of acid hydrolysis of β-d-glucopyranose in the aqueous solution.

Sign in / Sign up

Export Citation Format

Share Document