Methane Storage in Metal-Substituted Metal–Organic Frameworks: Thermodynamics, Usable Capacity, and the Impact of Enhanced Binding Sites

2014 ◽  
Vol 118 (6) ◽  
pp. 2929-2942 ◽  
Author(s):  
Malay Kumar Rana ◽  
Hyun Seung Koh ◽  
Haroon Zuberi ◽  
Donald J. Siegel
Keyword(s):  
Binding Sites ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
The Impact

scholarly journals Unravelling thermal stress due to thermal expansion mismatch in metal–organic frameworks for methane storage

2021 ◽  
Author(s):  
Jelle Wieme ◽  
Veronique Van Speybroeck
Keyword(s):  
Thermal Expansion ◽  
Thermal Stress ◽  
Pressure Coefficient ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Thermal Expansion Mismatch ◽  
Thermal Pressure ◽  
Temperature Changes ◽  
Metal Organic ◽  
The Impact

Thermal stress is present in metal–organic frameworks undergoing temperature changes during adsorption and desorption. We computed the thermal pressure coefficient as a proxy for this phenomenon and discuss the impact of thermal expansion mismatch.

Methane storage in flexible metal–organic frameworks with intrinsic thermal management

Nature ◽  
2015 ◽  
Vol 527 (7578) ◽  
pp. 357-361 ◽  
Author(s):  
Jarad A. Mason ◽  
Julia Oktawiec ◽  
Mercedes K. Taylor ◽  
Matthew R. Hudson ◽  
Julien Rodriguez ◽  
...  
Keyword(s):  
Thermal Management ◽  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Metal Organic ◽  
Flexible Metal

High Methane Storage Working Capacity in Metal–Organic Frameworks with Acrylate Links

2016 ◽  
Vol 138 (32) ◽  
pp. 10244-10251 ◽  
Author(s):  
Juncong Jiang ◽  
Hiroyasu Furukawa ◽  
Yue-Biao Zhang ◽  
Omar M. Yaghi
Keyword(s):  
Metal Organic Frameworks ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

scholarly journals Tailoring the pore geometry and chemistry in microporous metal–organic frameworks for high methane storage working capacity

2019 ◽  
Vol 55 (76) ◽  
pp. 11402-11405 ◽  
Author(s):  
Kai Shao ◽  
Jiyan Pei ◽  
Jia-Xin Wang ◽  
Yu Yang ◽  
Yuanjing Cui ◽  
...  
Keyword(s):  
Pore Size ◽  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Working Capacity ◽  
Metal Organic

We realized that engineering the pore size/geometry and chemistry in a series of MOFs can optimize the volumetric methane storage working capacity.

The impact of metal ions on photoinduced electron-transfer properties: four photochromic metal–organic frameworks based on a naphthalenediimide chromophore

CrystEngComm ◽  
2018 ◽  
Vol 20 (17) ◽  
pp. 2430-2439 ◽  
Author(s):  
Hui-Ling Xu ◽  
Xiao-Shan Zeng ◽  
Jie Li ◽  
Yu-Ci Xu ◽  
Hai-Jiang Qiu ◽  
...  
Keyword(s):  
Electron Transfer ◽  
Metal Ions ◽  
Significant Role ◽  
Photoinduced Electron Transfer ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Electron Transfer Properties ◽  
The Impact ◽  
Transfer Properties

Four photochromic MOFs show that electron-withdrawing capabilities of metal ions play a significant role in tuning the photosensitivity of photochromic MOFs.

Engineering of Pore Geometry for Ultrahigh Capacity Methane Storage in Mesoporous Metal–Organic Frameworks

2017 ◽  
Vol 139 (38) ◽  
pp. 13300-13303 ◽  
Author(s):  
Cong-Cong Liang ◽  
Zhao-Lin Shi ◽  
Chun-Ting He ◽  
Jing Tan ◽  
Hu-Die Zhou ◽  
...  
Keyword(s):  
Metal Organic Frameworks ◽  
Pore Geometry ◽  
Methane Storage ◽  
Metal Organic ◽  
Mesoporous Metal

Theoretical Insights into the Tuning of Metal Binding Sites of Paddlewheels inrht-Metal-Organic Frameworks

ChemPhysChem ◽  
2015 ◽  
Vol 16 (15) ◽  
pp. 3170-3179 ◽  
Author(s):  
Tony Pham ◽  
Katherine A. Forrest ◽  
Wen-Yang Gao ◽  
Shengqian Ma ◽  
Brian Space
Keyword(s):  
Metal Binding ◽  
Binding Sites ◽  
Metal Organic Frameworks ◽  
Metal Binding Sites ◽  
Metal Organic
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