Reactions of Hydrocarbon Radicals and Biradicals

2013 ◽  
Vol 117 (18) ◽  
pp. 3697-3717 ◽  
Author(s):  
Michael J. Pilling
Keyword(s):  
Author(s):  
A. E. Gorodetskii ◽  
V. L. Bukhovets ◽  
R. Kh. Zalavutdinov ◽  
A. P. Zakharov

Although arsenic and antimony exhibit certain similarities in regard to their combinations with hydrocarbon radicals yet the organic chemistry of the latter metalloid is still in a much more fragmentary condition than that of the former element because of the greater experimental difficulties which attend the preparation of organic antimonials. These difficulties are two-fold : the first is the ease with which antimony is dislodged from its attachment to carbon, the second arises from the amorphous and colloidal nature of organic stibinic acids. In a former communication* we discussed the antimonial analogues of the cacodyl series whereas in the present one we describe certain organic derivatives in which antimony replaces nitrogen in the carbazole nucleus, these compounds being analogues of the arsenical carbazole series already studied by Aeschlimann, Lees, McClelland and Nicklin.


2013 ◽  
Vol 117 (50) ◽  
pp. 13899-13907 ◽  
Author(s):  
Gerard D. O’Connor ◽  
George B. Bacskay ◽  
Gabrielle V. G. Woodhouse ◽  
Tyler P. Troy ◽  
Klaas Nauta ◽  
...  

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