Electronic Angular Momentum of Cyclic Aromatic Hydrocarbon Radicals and Ions

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pp. 541-543 ◽  
Author(s):  
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Thomas W. Dingle
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In the past few years theoretical aspects of the g-factors of aromatic hydrocarbon radicals have been developed. Since the g-factor variation of these radicals is only of the order of 10-4 precise measurements of these quantities are clearly called for. Absolute g-factor measurements are performed according to the equation g=C ω/ωp. A survey of the different determinations of the conversion factor C=2 γp′ m c/e is given and a value of C=3.0419890 × 10-3± 0.5 ppm is proposed for a well defined proton NMR probe. The most important effects are discussed which may shift the measured EPR and NMR frequencies ω and ωp.


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