Physicochemical Properties of Binary Ionic Liquid–Aprotic Solvent Electrolyte Mixtures

2012 ◽  
Vol 117 (1) ◽  
pp. 78-84 ◽  
Author(s):  
Eric T. Fox ◽  
Elie Paillard ◽  
Oleg Borodin ◽  
Wesley A. Henderson
Keyword(s):  
Ionic Liquid ◽  
Physicochemical Properties ◽  
Aprotic Solvent ◽  
Electrolyte Mixtures

Physicochemical properties of proton conducting membranes based on ionic liquid impregnated polymer for fuel cells

2006 ◽  
Vol 16 (23) ◽  
pp. 2256 ◽  
Author(s):  
S. S. Sekhon ◽  
Boor Singh Lalia ◽  
Jin-Soo Park ◽  
Chang-Soo Kim ◽  
K. Yamada
Keyword(s):  
Ionic Liquid ◽  
Fuel Cells ◽  
Physicochemical Properties ◽  
Proton Conducting ◽  
Conducting Membranes

Imidazolium-Based Ionic Liquid as Modulator of Physicochemical Properties of Cationic, Anionic, Nonionic, and Gemini Surfactants

2018 ◽  
Vol 21 (3) ◽  
pp. 355-366 ◽  
Author(s):  
Amit Kumar ◽  
Manoj K. Banjare ◽  
Srishti Sinha ◽  
Toshikee Yadav ◽  
Reshma Sahu ◽  
...  
Keyword(s):  
Ionic Liquid ◽  
Physicochemical Properties ◽  
Gemini Surfactants

Ionic liquid ion exchange: exclusion from strong interactions condemns cations to the most weakly interacting anions and dictates reaction equilibrium

2018 ◽  
Vol 20 (18) ◽  
pp. 4277-4286 ◽  
Author(s):  
Pieter Naert ◽  
Korneel Rabaey ◽  
Christian V. Stevens
Keyword(s):  
Ionic Liquid ◽  
Ion Exchange ◽  
Physicochemical Properties ◽  
Interaction Energy ◽  
Strong Interactions ◽  
Process Performance ◽  
Weakly Interacting ◽  
Reaction Equilibrium

Ion exchange is determined by the interaction energy and impacts process performance by change of physicochemical properties and reactivity.

scholarly journals Ionic Liquid Electrolytes for Safer and More Reliable Sodium Battery Systems

2020 ◽  
Vol 10 (18) ◽  
pp. 6323 ◽  
Author(s):  
Mariangela Bellusci ◽  
Elisabetta Simonetti ◽  
Massimo De Francesco ◽  
Giovanni Battista Appetecchi
Keyword(s):  
Thermal Stability ◽  
Ionic Liquid ◽  
Ionic Conductivity ◽  
Low Temperature ◽  
Room Temperature ◽  
Side Chain ◽  
Electrolyte Mixtures ◽  
Sodium Battery ◽  
Sodium Batteries ◽  
Battery Systems

Na+-conducting, binary electrolytic mixtures, based on 1-ethyl-3-methyl-imidazolium, trimethyl-butyl-ammonium, and N-alkyl-N-methyl-piperidinium ionic liquid (IL) families, were designed and investigated. The anions were selected among the per(fluoroalkylsulfonyl)imide families. Sodium bis(trifluoromethylsulfonyl)imide, NaTFSI, was selected as the salt. The NaTFSI-IL electrolytes, addressed to safer sodium battery systems, were studied and compared in terms of ionic conductivity and thermal stability as a function of the temperature, the nature of the anion and the cation aliphatic side chain length. Room temperature conductivities of interest for sodium batteries, i.e., largely overcoming 10−4 or 10−3 S cm−1, are displayed. Similar conduction values are exhibited by the EMI-based samples even below −10 °C, making these electrolyte mixtures potentially appealing also for low temperature applications. The NaTFSI-IL electrolytes, with the exception of the FSI-ones, are found to be thermally stable up to 275 °C, depending on the nature of the cation and/or anion, thus extending their applicability above 100 °C and remarkably increasing the reliability and safety of the final device, especially in the case of prolonged overheating.

scholarly journals The confinement and anion type effect on the physicochemical properties of ionic liquid/halloysite nanoclay ionogels

2020 ◽  
Vol 13 (12) ◽  
pp. 9090-9104
Author(s):  
A.V. Agafonov ◽  
N.O. Kudryakova ◽  
L.M. Ramenskaya ◽  
E.P. Grishina
Keyword(s):  
Ionic Liquid ◽  
Physicochemical Properties ◽  
Anion Type

Physicochemical properties of an N-decylpyridinium tetrachloroferrate ionic liquid

2014 ◽  
Vol 84 (6) ◽  
pp. 1141-1145 ◽  
Author(s):  
O. E. Zhuravlev ◽  
V. M. Nikol’skii ◽  
L. I. Voronchikhina
Keyword(s):  
Ionic Liquid ◽  
Physicochemical Properties
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