Magnesium Hydride Formation within Carbon Aerogel

2011 ◽  
Vol 115 (5) ◽  
pp. 1757-1766 ◽  
Author(s):  
Mark Paskevicius ◽  
Hu-Yong Tian ◽  
Drew A. Sheppard ◽  
Colin J. Webb ◽  
Mark P. Pitt ◽  
...  
Keyword(s):  
Carbon Aerogel ◽  
Magnesium Hydride ◽  
Hydride Formation

scholarly journals Nanometer-scale hydrogen ‘portals’ for the control of magnesium hydride formation

2015 ◽  
Vol 17 (43) ◽  
pp. 28977-28984 ◽  
Author(s):  
Chia-Jung Chung ◽  
Chinmay Nivargi ◽  
Bruce Clemens
Keyword(s):  
Thin Films ◽  
Pd Nanoparticles ◽  
Magnesium Hydride ◽  
Nanometer Scale ◽  
Hydride Formation ◽  
Formation Kinetics

Our unique ‘nanoportal’ structure of Pd nanoparticles deposited on epitaxial Mg thin films allows the study of MgH2 formation kinetics in a controlled way.

scholarly journals Real Space Observations of Magnesium Hydride Formation and Decomposition

2010 ◽  
Vol 22 (4) ◽  
pp. 1291-1293 ◽  
Author(s):  
T. Herranz ◽  
K. F. McCarty ◽  
B. Santos ◽  
M. Monti ◽  
J. de la Figuera
Keyword(s):  
Real Space ◽  
Magnesium Hydride ◽  
Hydride Formation ◽  
Space Observations

scholarly journals In Situ Formation of Metal Hydrides Inside Carbon Aerogel Frameworks for Hydrogen Storage Applications

2020 ◽  
Vol 6 (2) ◽  
pp. 38
Author(s):  
Mohammad Reza Ghaani ◽  
Mahdi Alam ◽  
Michele Catti ◽  
Niall J. English
Keyword(s):  
Electron Microscopy ◽  
Scanning Electron Microscopy ◽  
Surface Area ◽  
Carbon Aerogel ◽  
Carbon Aerogels ◽  
Great Promise ◽  
Hydride Formation ◽  
Wide Range ◽  
Scanning Electron

Nano-confined chemical reactions bear great promise for a wide range of important applications in the near-to-medium term, e.g., within the emerging area of chemical storage of renewable energy. To explore this important trend, in the present work, resorcinol-/formaldehyde-based carbon aerogels were prepared by sol-gel polymerisation of resorcinol, with furfural catalysed by a sodium-carbonate solution using ambient-pressure drying. These aerogels were further carbonised in nitrogen to obtain their corresponding carbon aerogels. Through this study, the synthesis parameters were selected in a way to obtain minimum shrinkage during the drying step. The microstructure of the product was observed using Scanning Electron Microscopy (SEM) and Field Emission Scanning Electron Microscopy (FESEM) imaging techniques. The optimised carbon aerogels were found to have pore sizes of ~21 nm with a specific accessible surface area equal to 854.0 m2/g. Physical activation of the carbon aerogel with CO2 generates activated carbon aerogels with a surface area of 1756 m2/g and a total porosity volume up to 3.23 cm3/g. The product was then used as a scaffold for magnesium/cobalt-hydride formation. At first, cobalt nanoparticles were formed inside the scaffold, by reducing the confined cobalt oxide, then MgH2 was synthesised as the second required component in the scaffold, by infiltrating the solution of dibutyl magnesium (MgBu2) precursor, followed by a hydrogenation reaction. Further hydrogenation at higher temperature leads to the formation of Mg2CoH5. In situ synchrotron X-ray diffraction was employed to study the mechanism of hydride formation during the heating process.

scholarly journals Mathematical Modelling of Titanium Hydride Formation from Titanium Tetrachloride with Magnesium Hydride using Matlab

2018 ◽  
Vol 1082 ◽  
pp. 012037
Author(s):  
Sanjith Udayakumar ◽  
Atif Sadaqi ◽  
Najwa Ibrahim ◽  
M. N. Ahmad Fauzi ◽  
Sivakumar Ramakrishnan ◽  
...  
Keyword(s):  
Mathematical Modelling ◽  
Titanium Hydride ◽  
Titanium Tetrachloride ◽  
Magnesium Hydride ◽  
Hydride Formation

Non-cyclopentadienyl Titanium(III)−Magnesium Hydride Formation by Reduction of an Amidotitanium(IV) Complex

2003 ◽  
Vol 22 (22) ◽  
pp. 4387-4389 ◽  
Author(s):  
Q. Folashade Mokuolu ◽  
Paul A. Duckmanton ◽  
Alexander J. Blake ◽  
Claire Wilson ◽  
Jason B. Love
Keyword(s):  
Magnesium Hydride ◽  
Hydride Formation

Effect of Group IIIA metal additives on the kinetics of magnesium hydride formation

1978 ◽  
Vol 40 (11) ◽  
pp. 1949-1951 ◽  
Author(s):  
M.H. Mintz ◽  
S. Malkiely ◽  
Z. Gavra ◽  
Z. Hadari
Keyword(s):  
Magnesium Hydride ◽  
Hydride Formation ◽  
Metal Additives ◽  
Kinetics Of

Hydrogen diffusion kinetics under different conditions applied to VT6 alloy

2020 ◽  
pp. 98-107
Author(s):  
E. I. Maslikova ◽  
V. D. Andreeva ◽  
E. L. Alekseeva ◽  
Yu. A. Yakovlev
Keyword(s):  
Heat Treatment ◽  
Oxide Film ◽  
Titanium Alloys ◽  
Hydrogen Diffusion ◽  
Heat Treating ◽  
Protective Atmosphere ◽  
Diffusion Kinetics ◽  
Hydrogen Charging ◽  
Hydride Formation ◽  
Different Types

Research of hydrogen diffusion in VT6 alloy is carried out considering different types of heat treating and hydrogen charging. The influence of microalloying on the susceptibility to hydride formation and embrittlement of titanium alloys is analyzed, and also effects of an oxide film on hydrogen charging during heat treatment without protective atmosphere, are studied.

Capacitance control of carbon aerogel electrodes

2004 ◽  
Vol 347 (1-3) ◽  
pp. 238-245 ◽  
Author(s):  
Sung-Woo Hwang ◽  
Sang-Hoon Hyun
Keyword(s):  
Carbon Aerogel
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