ChemInform Abstract: EFFECT OF GROUP IIIA METAL ADDITIVES ON THE KINETICS OF MAGNESIUM HYDRIDE FORMATION

1979 ◽  
Vol 10 (8) ◽  
Author(s):  
M. H. MINTZ ◽  
S. MALKIELY ◽  
Z. GAVRA ◽  
Z. HADARI
Keyword(s):  
Magnesium Hydride ◽  
Hydride Formation ◽  
Metal Additives ◽  
Kinetics Of

Effect of Group IIIA metal additives on the kinetics of magnesium hydride formation

1978 ◽  
Vol 40 (11) ◽  
pp. 1949-1951 ◽  
Author(s):  
M.H. Mintz ◽  
S. Malkiely ◽  
Z. Gavra ◽  
Z. Hadari
Keyword(s):  
Magnesium Hydride ◽  
Hydride Formation ◽  
Metal Additives ◽  
Kinetics Of

scholarly journals Atoms and Nanoparticles of Transition Metals as Catalysts for Hydrogen Desorption from Magnesium Hydride

2011 ◽  
Vol 2011 ◽  
pp. 1-11 ◽  
Author(s):  
N. Bazzanella ◽  
R. Checchetto ◽  
A. Miotello
Keyword(s):  
Composite Materials ◽  
Transition Metal ◽  
Transition Metals ◽  
Hydrogen Desorption ◽  
Magnesium Hydride ◽  
Desorption Kinetics ◽  
Fast Diffusion ◽  
Desorption Process ◽  
Metal Additives ◽  
Kinetics Of

The hydrogen desorption kinetics of composite materials made of magnesium hydride with transition metal additives (TM: Nb, Fe, and Zr) was studied by several experimental techniques showing that (i) a few TM at.% concentrations catalyse the H2desorption process, (ii) the H2desorption kinetics results stabilized after a few H2sorption cycles when TM atoms aggregate by forming nanoclusters; (iii) the catalytic process occurs also at TM concentration as low as 0.06 at.% when TM atoms clustering is negligible, and (iv) mixed Fe and Zr additives produce faster H2desorption kinetics than single additive. The improved H2desorption kinetics of the composite materials can be explained by assuming that the interfaces between the MgH2matrix and the TM nanoclusters act as heterogeneous sites for the nucleation of the Mg phase in the MgH2matrix and promote the formation of fast diffusion channels for H migrating atoms.

scholarly journals Nanometer-scale hydrogen ‘portals’ for the control of magnesium hydride formation

2015 ◽  
Vol 17 (43) ◽  
pp. 28977-28984 ◽  
Author(s):  
Chia-Jung Chung ◽  
Chinmay Nivargi ◽  
Bruce Clemens
Keyword(s):  
Thin Films ◽  
Pd Nanoparticles ◽  
Magnesium Hydride ◽  
Nanometer Scale ◽  
Hydride Formation ◽  
Formation Kinetics

Our unique ‘nanoportal’ structure of Pd nanoparticles deposited on epitaxial Mg thin films allows the study of MgH2 formation kinetics in a controlled way.

Hydrogen sorption kinetics of magnesium hydride enhanced by the addition of Zr 8 Ni 21 alloy

2012 ◽  
Vol 530 ◽  
pp. 111-115 ◽  
Author(s):  
S.A. Pighin ◽  
G. Capurso ◽  
S. Lo Russo ◽  
H.A. Peretti
Keyword(s):  
Sorption Kinetics ◽  
Magnesium Hydride ◽  
Hydrogen Sorption ◽  
Kinetics Of

scholarly journals Real Space Observations of Magnesium Hydride Formation and Decomposition

2010 ◽  
Vol 22 (4) ◽  
pp. 1291-1293 ◽  
Author(s):  
T. Herranz ◽  
K. F. McCarty ◽  
B. Santos ◽  
M. Monti ◽  
J. de la Figuera
Keyword(s):  
Real Space ◽  
Magnesium Hydride ◽  
Hydride Formation ◽  
Space Observations
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