Time Resolved in Situ XAFS Study of the Electrochemical Oxygen Intercalation in SrFeO2.5 Brownmillerite Structure: Comparison with the Homologous SrCoO2.5 System

2010 ◽  
Vol 115 (4) ◽  
pp. 1311-1322 ◽  
Author(s):  
Andrea Piovano ◽  
Giovanni Agostini ◽  
Anatoly I. Frenkel ◽  
Tanguy Bertier ◽  
Carmelo Prestipino ◽  
...  
Keyword(s):  
Structure Comparison ◽  
Time Resolved ◽  
In Situ Xafs ◽  
Oxygen Intercalation ◽  
Brownmillerite Structure ◽  
Electrochemical Oxygen

scholarly journals On the mechanism of rapid metal exchange between thiolate-protected gold and gold/silver clusters: a time-resolved in situ XAFS study

2018 ◽  
Vol 20 (7) ◽  
pp. 5312-5318 ◽  
Author(s):  
Bei Zhang ◽  
Olga V. Safonova ◽  
Stephan Pollitt ◽  
Giovanni Salassa ◽  
Annelies Sels ◽  
...  
Keyword(s):  
Exchange Reaction ◽  
Silver Clusters ◽  
Metal Exchange ◽  
Time Resolved ◽  
X Ray ◽  
Gold Silver ◽  
In Situ Xafs ◽  
Metal Exchange Reaction ◽  
X Ray Absorption

The fast metal exchange reaction between Au38 and AgxAu38−x nanoclusters has been studied by time resolved in situ X-ray absorption spectroscopy.

Time-Resolved in Situ Studies of Oxygen Intercalation into SrCoO2.5, Performed by Neutron Diffraction and X-ray Absorption Spectroscopy

2006 ◽  
Vol 128 (40) ◽  
pp. 13161-13174 ◽  
Author(s):  
Ronan Le Toquin ◽  
Werner Paulus ◽  
Alain Cousson ◽  
Carmelo Prestipino ◽  
Carlo Lamberti
Keyword(s):  
Neutron Diffraction ◽  
Absorption Spectroscopy ◽  
Time Resolved ◽  
X Ray ◽  
In Situ Studies ◽  
Oxygen Intercalation ◽  
X Ray Absorption

scholarly journals Solid-state reactivity explored in situ by synchrotron radiation on single crystals of SrFeO2.5 during electrochemical oxygen intercalation    

2016 ◽  
Vol 72 (a1) ◽  
pp. s421-s421
Author(s):  
Avishek Maity ◽  
Rajesh Dutta ◽  
Bartosz Penkala ◽  
Monica Ceretti ◽  
Angélique Letrouit-Lebranchu ◽  
...  
Keyword(s):  
Solid State ◽  
Synchrotron Radiation ◽  
Single Crystals ◽  
Oxygen Intercalation ◽  
Electrochemical Oxygen

Exciton dynamics in thick GaN MOVPE epilayers deposited on sapphire.

1997 ◽  
Vol 2 ◽  
Author(s):  
J. Allègre ◽  
P. Lefebvre ◽  
J. Camassel ◽  
B. Beaumont ◽  
Pierre Gibart
Keyword(s):  
Layer Thickness ◽  
Buffer Layers ◽  
Rate Equations ◽  
Time Resolved ◽  
Versus Layer ◽  
Level Model ◽  
Shallow Impurities ◽  
Aln Buffer ◽  
Time Resolved Photoluminescence

Time-resolved photoluminescence spectra have been recorded on three GaN epitaxial layers of thickness 2.5 μm, 7 μm and 16 μm, at various temperatures ranging from 8K to 300K. The layers were deposited by MOVPE on (0001) sapphire substrates with standard AlN buffer layers. To achieve good homogeneities, the growth was in-situ monitored by laser reflectometry. All GaN layers showed sharp excitonic peaks in cw PL and three excitonic contributions were seen by reflectivity. The recombination dynamics of excitons depends strongly upon the layer thickness. For the thinnest layer, exponential decays with τ ~ 35 ps have been measured for both XA and XB free excitons. For the thickest layer, the decay becomes biexponential with τ1 ~ 80 ps and τ2 ~ 250 ps. These values are preserved up to room temperature. By solving coupled rate equations in a four-level model, this evolution is interpreted in terms of the reduction of density of both shallow impurities and deep traps, versus layer thickness, roughly following a L−1 law.

Monitoring Polymer-Assisted Mechanochemical Cocrystallisation Through in Situ X-Ray Powder Diffraction

2020 ◽  
Author(s):  
Luzia S. Germann ◽  
Sebastian T. Emmerling ◽  
Manuel Wilke ◽  
Robert E. Dinnebier ◽  
Mariarosa Moneghini ◽  
...  
Keyword(s):  
Molecular Weight ◽  
Powder Diffraction ◽  
Reaction Rate ◽  
Polymer Additives ◽  
Time Resolved ◽  
X Ray

Time-resolved mechanochemical cocrystallisation studies have so-far focused solely on neat and liquid-assisted grinding. Here, we report the monitoring of polymer-assisted grinding reactions using <i>in situ</i> X-ray powder diffraction, revealing that reaction rate is almost double compared to neat grinding and independent of the molecular weight and amount of used polymer additives.<br>

In situ Time-Resolved Small-Angle X-ray Scattering Reveals the Formation Kinetics of Polyelectrolyte Complex Micelles

2019 ◽  
Author(s):  
Hao Wu ◽  
Jeffrey Ting ◽  
Siqi Meng ◽  
Matthew Tirrell
Keyword(s):  
Small Angle ◽  
Self Assembly ◽  
Electrostatic Interactions ◽  
Polyelectrolyte Complex ◽  
Time Resolved ◽  
X Ray ◽  
X Ray Scattering ◽  
Kinetics Of ◽  
Ray Scattering

We have directly observed the <i>in situ</i> self-assembly kinetics of polyelectrolyte complex (PEC) micelles by synchrotron time-resolved small-angle X-ray scattering, equipped with a stopped-flow device that provides millisecond temporal resolution. This work has elucidated one general kinetic pathway for the process of PEC micelle formation, which provides useful physical insights for increasing our fundamental understanding of complexation and self-assembly dynamics driven by electrostatic interactions that occur on ultrafast timescales.

Kinetic analysis of Ag particle redispersion into ZSM-5 in the presence of coke using in situ XAFS

2021 ◽  
Author(s):  
Kazumasa Murata ◽  
Junya Ohyama ◽  
Atsushi Satsuma
Keyword(s):  
Fine Structure ◽  
Kinetic Analysis ◽  
X Ray ◽  
Xafs Spectroscopy ◽  
Absorption Fine ◽  
Ag Particles ◽  
In Situ Xafs ◽  
Ag Particle ◽  
X Ray Absorption

In the present study, the redispersion behavior of Ag particles on ZSM-5 in the presence of coke was observed using in situ X-ray absorption fine structure (XAFS) spectroscopy.

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