Direct Time-Resolved Study of the Gas-Phase Reactions of Germylene with Ethyl- and Diethylgermane:  Absolute Rate Constants, Temperature Dependences, and Mechanism

2007 ◽  
Vol 111 (8) ◽  
pp. 1434-1440 ◽  
Author(s):  
Rosa Becerra ◽  
Sergey E. Boganov ◽  
Mikhail P. Egorov ◽  
Irina V. Krylova ◽  
Oleg M. Nefedov ◽  
...  
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Time Resolved ◽  
Temperature Dependences

The reactions of O(3P) with the butanols

1983 ◽  
Vol 61 (12) ◽  
pp. 2716-2720 ◽  
Author(s):  
John M. Roscoe
Keyword(s):  
Free Energy ◽  
Gas Phase ◽  
Rate Constants ◽  
Substrate Concentration ◽  
Kinetic Data ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Linear Free Energy ◽  
Different Types ◽  
Energy Relations

The reactions of O(3P) with the butanols were studied kinetically as a function of temperature and substrate concentration. The absolute rate constants for the gas phase reactions, in the units M−1 s−1, obey the following relations.[Formula: see text]The results suggest that although the α-CH bond in these alcohols is the most reactive one, reaction of O(3P) with other CH bonds in the alcohols is also appreciable. The kinetic data for these and other alcohols are separated into contributions from the different types of CH bonds and the results are discussed in terms of linear free energy relations.

Absolute rate determinations and temperature dependences of the gas-phase reactions of O(3P) with halogenated propenes

2006 ◽  
Vol 417 (4-6) ◽  
pp. 480-485 ◽  
Author(s):  
Pablo M. Cometto ◽  
Mariano A. Teruel ◽  
Raúl A. Taccone ◽  
Silvia I. Lane
Keyword(s):  
Gas Phase ◽  
Absolute Rate ◽  
Gas Phase Reactions ◽  
Temperature Dependences

Kinetics and Rate Constants of Reactions Leading to Hydration of and in Gaseous Oxygen, Argon, and Helium Containing Traces of Water

1972 ◽  
Vol 50 (14) ◽  
pp. 2230-2235 ◽  
Author(s):  
J. D. Payzant ◽  
A. J. Cunningham ◽  
P. Kebarle
Keyword(s):  
High Pressure ◽  
Electron Beam ◽  
Gas Phase ◽  
Mass Spectrometer ◽  
Rate Constants ◽  
Gas Phase Reactions ◽  
Third Order ◽  
Gaseous Oxygen ◽  
Time Resolved ◽  
Pulsed Electron Beam

The rate constants for the forward and reverse components of gas phase reactions:[Formula: see text]were measured with a pulsed electron beam, time resolved detection high pressure mass spectrometer at 300 °K. O2, Ar, and He at pressures from 1–7 Torr were used as third gas M. The forward reactions were found to be third order and the reverse reactions second order. Establishment of the equilibria could also be observed.

Absolute rate constants for the gas-phase reactions of silylene with silane, disilane and the methylsilanes

1990 ◽  
Vol 86 (1) ◽  
pp. 27 ◽  
Author(s):  
James E. Baggott ◽  
H. Monty Frey ◽  
Phillip D. Lightfoot ◽  
Robin Walsh ◽  
Ivy M. Watts
Keyword(s):  
Gas Phase ◽  
Rate Constants ◽  
Absolute Rate ◽  
Gas Phase Reactions
Sign in / Sign up

Export Citation Format

Share Document