A Two-Step Spin Transition with a Disordered Intermediate State in a New Two-Dimensional Coordination Polymer

2007 ◽  
Vol 111 (6) ◽  
pp. 1256-1261 ◽  
Author(s):  
J. Alberto Rodríguez-Velamazán ◽  
Miguel Castro ◽  
Elías Palacios ◽  
Ramón Burriel ◽  
Takafumi Kitazawa ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Intermediate State ◽  
Spin Transition ◽  
Two Dimensional

Thermal, pressure and light induced spin transition in the two-dimensional coordination polymer {Fe(pmd)2[Cu(CN)2]2}

2008 ◽  
pp. 642-649 ◽  
Author(s):  
Gloria Agustí ◽  
Amber L. Thompson ◽  
Ana B. Gaspar ◽  
M. Carmen Muñoz ◽  
Andrés E. Goeta ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Transition ◽  
Two Dimensional ◽  
Thermal Pressure

Variable Cooperative Interactions in the Pressure and Thermally Induced Multistep Spin Transition in a Two-Dimensional Iron(II) Coordination Polymer

2020 ◽  
Vol 59 (15) ◽  
pp. 10548-10556 ◽  
Author(s):  
Mengyun Yuan ◽  
Georgiy Levchenko ◽  
Quanjun Li ◽  
Ludmila Berezhnaya ◽  
Hennagii Fylymonov ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Transition ◽  
Two Dimensional ◽  
Thermally Induced ◽  
Cooperative Interactions

Cooperative Spin Transition in the Two-Dimensional Coordination Polymer [Fe(4,4′-bipyridine)2(NCX)2]·4CHCl3(X = S, Se)

2011 ◽  
Vol 50 (21) ◽  
pp. 10633-10642 ◽  
Author(s):  
Christopher J. Adams ◽  
M. Carmen Muñoz ◽  
Rachel E. Waddington ◽  
José Antonio Real
Keyword(s):  
Coordination Polymer ◽  
Spin Transition ◽  
Two Dimensional

A spin-crossover phenomenon in a 2D heterometallic coordination polymer with [Pd(SCN)4]2− building blocks

2021 ◽  
Vol 50 (12) ◽  
pp. 4152-4158
Author(s):  
Kai-Ping Xie ◽  
Si-Guo Wu ◽  
Long-Fei Wang ◽  
Guo-Zhang Huang ◽  
Zhao-Ping Ni ◽  
...  
Keyword(s):  
Coordination Polymer ◽  
Spin Crossover ◽  
Building Blocks ◽  
Two Dimensional ◽  
Heterometallic Coordination Polymer

The first spin-crossover example of a two-dimensional coordination polymer containing [Pd(SCN)4]2− building blocks was explored.

scholarly journals Crystal structure of two-dimensional coordination polymer poly-[μ2-azido-aqua-(μ2-pyrazine-2-carboxylato-κ3O,N:N′)nickel(II)], C5H5N5O3Ni

2016 ◽  
Vol 231 (4) ◽  
pp. 1163-1164
Author(s):  
Yu Youzhu ◽  
Guo Yuhua ◽  
Yang Liguo ◽  
Niu Yongsheng
Keyword(s):  
Crystal Structure ◽  
Coordination Polymer ◽  
Two Dimensional

AbstractC5H5N5O3Ni, monoclinic, C2/c (no. 15), a = 8.5804(17) Å, b = 13.790(3) Å, c = 13.969(3) Å, β = 104.37(3)°, V =1601.2(6)Å3, Z = 8, Rgt(F) = 0.0203, wRref(F2) = 0.0550, T = 293 K.

A two-dimensional CdII coordination polymer with 2,2′-(disulfanediyl)dibenzoate and 1,10-phenanthroline ligands

2014 ◽  
Vol 70 (5) ◽  
pp. 517-521
Author(s):  
Yu-Xiu Jin ◽  
Fang Yang ◽  
Li-Min Yuan ◽  
Chao-Guo Yan ◽  
Wen-Long Liu
Keyword(s):  
Coordination Polymer ◽  
Three Dimensional ◽  
Phen Ligand ◽  
Supramolecular Architecture ◽  
Two Dimensional ◽  
Asymmetric Unit ◽  
Π Interactions ◽  
Carboxylate Groups ◽  
Phenanthroline Ligand ◽  
Phenanthroline Ligands

In poly[[μ3-2,2′-(disulfanediyl)dibenzoato-κ5 O:O,O′:O′′,O′′′](1,10-phenanthroline-κ2 N,N′)cadmium(II)], [Cd(C14H8O4S2)(C12H8N2)] n , the asymmetric unit contains one CdII cation, one 2,2′-(disulfanediyl)dibenzoate anion (denoted dtdb2−) and one 1,10-phenanthroline ligand (denoted phen). Each CdII centre is seven-coordinated by five O atoms of bridging/chelating carboxylate groups from three dtdb2− ligands and by two N atoms from one phen ligand, forming a distorted pentagonal–bipyramidal geometry. The CdII cations are bridged by dtdb2− anions to give a two-dimensional (4,4) layer. The layers are stacked to generate a three-dimensional supramolecular architecture via a combination of aromatic C—H...π and π–π interactions. The thermogravimetric and luminescence properties of this compound were also investigated.

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